@article{e4f36ec8efe84b62bc00bee4829ee76d,
title = "Glycerol Oxidation Catalyzed by High-valency Ruthenium Species at Electrochemical Interfaces",
abstract = "Herein we report high-valency ruthenium (Ru) species as a new class of electrocatalyst for glycerol oxidation. In this study, Ru-modified covalent triazine framework (Ru-CTF) and ruthenium oxide supported on carbon (RuO2/C) were used as model materials with high-valency Ru species. The results of this work show that the deep oxidation reactions of glycerol involving C-C bond cleavage can be effectively suppressed by increasing the glycerol concentration relative to the number of active Ru atoms for both catalysts.",
keywords = "Electrocatalyst, Glycerol, Ruthenium",
author = "Hiro Tabata and Shintaro Kato and Shingi Yamaguchi and Takashi Harada and Kazuyuki Iwase and Kazuhide Kamiya and Shuji Nakanishi",
note = "Funding Information: This research was supported by CREST (grant no. JPMJCR18R3) of the Japan Science and Technology Agency (JST) and a JSPS KAKENHI Program (grant no. 17H04798). We thank Dr. T. Ina for providing technical support with the XAFS measurements at SPring-8. TEM inspections were carried out using a facility in the Research Center for Ultra-High Voltage Electron Microscopy, Osaka University, under the guidance by Dr. T. Sakata. Synchrotron radiation experiments were performed using the BL01B1 Beam Line of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI; Proposal Nos. 2018A1349, 2019A1394, and 2019B1159). Publisher Copyright: {\textcopyright} 2020 The Chemical Society of Japan.",
year = "2020",
month = may,
doi = "10.1246/cl.200056",
language = "English",
volume = "49",
pages = "513--516",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "5",
}