Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

Rockshana Begum, Takashi Komuro, Hiromi Tobita

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

The synthesis and characterization of tungsten and molybdenum complexes of the xanthene-based bis(silyl) ligand (xantsil) with a κ3(Si,Si, O) coordination mode are reported, where an insertion of tBuCN into a tungsten-silicon bond leads to formation of an η2-iminoacyl complex.

Original languageEnglish
Pages (from-to)432-433
Number of pages2
JournalChemical Communications
Issue number4
DOIs
Publication statusPublished - 2006

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