TY - JOUR
T1 - Hexagonal layered materials composed of [M2(O2CCF3)4] (M = Ru and Rh) donors and TCNQ acceptors
AU - Miyasaka, Hitoshi
AU - Campos-Fernández, Cristian S.
AU - Clérac, Rodolphe
AU - Dunbar, Kim R.
PY - 2000/11/3
Y1 - 2000/11/3
N2 - Delocalization throughout the extended layers of two-dimensional network polymers of the type [{M2(O2CCF3)4}2(TCNQ)·3(C7H8)]∞, which consist of Ru(II), Ru(II) and Rh(II), Rh(II) complexes coordinated to TCNQ molecules, is evident from the available structural (see picture for Ru analogue) and spectroscopic data. TCNQ = 7, 7, 8, 8-tetracyano-p-quinodimethane.
AB - Delocalization throughout the extended layers of two-dimensional network polymers of the type [{M2(O2CCF3)4}2(TCNQ)·3(C7H8)]∞, which consist of Ru(II), Ru(II) and Rh(II), Rh(II) complexes coordinated to TCNQ molecules, is evident from the available structural (see picture for Ru analogue) and spectroscopic data. TCNQ = 7, 7, 8, 8-tetracyano-p-quinodimethane.
KW - Charge transfer
KW - Delocalization
KW - N ligands
KW - Rhodium
KW - Ruthenium
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U2 - 10.1002/1521-3773(20001103)39:21<3831::AID-ANIE3831>3.0.CO;2-D
DO - 10.1002/1521-3773(20001103)39:21<3831::AID-ANIE3831>3.0.CO;2-D
M3 - Article
AN - SCOPUS:0034602046
SN - 1433-7851
VL - 39
SP - 3831
EP - 3835
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 21
ER -