Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: Asymmetric entry to the spiro-β-lactam core of chartellines

Shigeki Sato; Masatoshi Shibuya; Naoki Kanoh; Yoshiharu Iwabuchi

doi:10.1039/b913770j

Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: Asymmetric entry to the spiro-β-lactam core of chartellines

Shigeki Sato, Masatoshi Shibuya, Naoki Kanoh, Yoshiharu Iwabuchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

Original language	English
Pages (from-to)	6264-6266
Number of pages	3
Journal	Chemical Communications
Issue number	41
DOIs	https://doi.org/10.1039/b913770j
Publication status	Published - 2009 Oct 19

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b913770j

Cite this

@article{016c28ca0b3e4a68a296a4db32fedb23,

title = "Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: Asymmetric entry to the spiro-β-lactam core of chartellines",

abstract = "A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.",

author = "Shigeki Sato and Masatoshi Shibuya and Naoki Kanoh and Yoshiharu Iwabuchi",

year = "2009",

month = oct,

day = "19",

doi = "10.1039/b913770j",

language = "English",

pages = "6264--6266",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "41",

}

TY - JOUR

T1 - Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis

T2 - Asymmetric entry to the spiro-β-lactam core of chartellines

AU - Sato, Shigeki

AU - Shibuya, Masatoshi

AU - Kanoh, Naoki

AU - Iwabuchi, Yoshiharu

PY - 2009/10/19

Y1 - 2009/10/19

N2 - A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

AB - A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

UR - http://www.scopus.com/inward/record.url?scp=70349920648&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70349920648&partnerID=8YFLogxK

U2 - 10.1039/b913770j

DO - 10.1039/b913770j

M3 - Article

C2 - 19826689

AN - SCOPUS:70349920648

SN - 1359-7345

SP - 6264

EP - 6266

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: Asymmetric entry to the spiro-β-lactam core of chartellines

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this