Highly selective hydrothermal production of cyclohexanol from biomass-derived cyclohexanone over Cu powder

Zhiyuan Song; Dezhang Ren; Tian Wang; Fangming Jin; Qianhui Jiang; Zhibao Huo

doi:10.1016/j.cattod.2015.11.016

Highly selective hydrothermal production of cyclohexanol from biomass-derived cyclohexanone over Cu powder

Zhiyuan Song, Dezhang Ren, Tian Wang, Fangming Jin, Qianhui Jiang, Zhibao Huo

ENV - Environmental Studies for Advanced Society

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

An efficient conversion of biomass-derived cyclohexanone to cyclohexanol by in situ-formed hydrogen over Cu catalyst under hydrothermal conditions was reported at first. Among the catalysts tested, Cu exhibited high catalytic activity for the conversion of cyclohexanone, and the highest yield of 100% was obtained when Zn acted as reductant. The experiment was carried out by using gaseous hydrogen as the external hydrogen source indicated that the yield of 75.1% was lower than in situ-formed hydrogen by oxidation of Zn in water. The present study provides an efficient route by environmentally benign, commercially available Cu powder as a catalyst for cyclohexanone conversion to cyclohexanol.

Original language	English
Pages (from-to)	94-98
Number of pages	5
Journal	Catalysis Today
Volume	274
DOIs	https://doi.org/10.1016/j.cattod.2015.11.016
Publication status	Published - 2016 Oct 1

Keywords

Biomass derivatives
Cu powder
Cyclohexanol
Cyclohexanone
Hydrothermal reaction

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1016/j.cattod.2015.11.016

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title = "Highly selective hydrothermal production of cyclohexanol from biomass-derived cyclohexanone over Cu powder",

abstract = "An efficient conversion of biomass-derived cyclohexanone to cyclohexanol by in situ-formed hydrogen over Cu catalyst under hydrothermal conditions was reported at first. Among the catalysts tested, Cu exhibited high catalytic activity for the conversion of cyclohexanone, and the highest yield of 100% was obtained when Zn acted as reductant. The experiment was carried out by using gaseous hydrogen as the external hydrogen source indicated that the yield of 75.1% was lower than in situ-formed hydrogen by oxidation of Zn in water. The present study provides an efficient route by environmentally benign, commercially available Cu powder as a catalyst for cyclohexanone conversion to cyclohexanol.",

keywords = "Biomass derivatives, Cu powder, Cyclohexanol, Cyclohexanone, Hydrothermal reaction",

author = "Zhiyuan Song and Dezhang Ren and Tian Wang and Fangming Jin and Qianhui Jiang and Zhibao Huo",

note = "Funding Information: Supported by the State Key Program of National Natural Science Foundation of China (Grant No. 21436007). Key Basic ResearchProjects of Science and Technology Commission of Shanghai(14JC1403100). The Program for Professor of Special Appoint-ment (Eastern Scholar) at Shanghai Institutions of Higher Learning(ZXDF160002). The Project-sponsored by SRF for ROCS, SEM(BG1600002). Publisher Copyright: {\textcopyright} 2015 Elsevier B.V. All rights reserved. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2016",

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day = "1",

doi = "10.1016/j.cattod.2015.11.016",

language = "English",

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AU - Song, Zhiyuan

AU - Ren, Dezhang

AU - Wang, Tian

AU - Jin, Fangming

AU - Jiang, Qianhui

AU - Huo, Zhibao

N1 - Funding Information: Supported by the State Key Program of National Natural Science Foundation of China (Grant No. 21436007). Key Basic ResearchProjects of Science and Technology Commission of Shanghai(14JC1403100). The Program for Professor of Special Appoint-ment (Eastern Scholar) at Shanghai Institutions of Higher Learning(ZXDF160002). The Project-sponsored by SRF for ROCS, SEM(BG1600002). Publisher Copyright: © 2015 Elsevier B.V. All rights reserved. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2016/10/1

Y1 - 2016/10/1

N2 - An efficient conversion of biomass-derived cyclohexanone to cyclohexanol by in situ-formed hydrogen over Cu catalyst under hydrothermal conditions was reported at first. Among the catalysts tested, Cu exhibited high catalytic activity for the conversion of cyclohexanone, and the highest yield of 100% was obtained when Zn acted as reductant. The experiment was carried out by using gaseous hydrogen as the external hydrogen source indicated that the yield of 75.1% was lower than in situ-formed hydrogen by oxidation of Zn in water. The present study provides an efficient route by environmentally benign, commercially available Cu powder as a catalyst for cyclohexanone conversion to cyclohexanol.

AB - An efficient conversion of biomass-derived cyclohexanone to cyclohexanol by in situ-formed hydrogen over Cu catalyst under hydrothermal conditions was reported at first. Among the catalysts tested, Cu exhibited high catalytic activity for the conversion of cyclohexanone, and the highest yield of 100% was obtained when Zn acted as reductant. The experiment was carried out by using gaseous hydrogen as the external hydrogen source indicated that the yield of 75.1% was lower than in situ-formed hydrogen by oxidation of Zn in water. The present study provides an efficient route by environmentally benign, commercially available Cu powder as a catalyst for cyclohexanone conversion to cyclohexanol.

KW - Biomass derivatives

KW - Cu powder

KW - Cyclohexanol

KW - Cyclohexanone

KW - Hydrothermal reaction

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SN - 0920-5861

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EP - 98

JO - Catalysis Today

JF - Catalysis Today

ER -

Highly selective hydrothermal production of cyclohexanol from biomass-derived cyclohexanone over Cu powder

Abstract

Keywords

ASJC Scopus subject areas

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