TY - JOUR
T1 - Hybrid quantum control of photodesorption of NO from a metal surface
AU - Nakagami, Kazuyuki
AU - Ohtsuki, Yukiyoshi
AU - Fujimura, Yuichi
N1 - Funding Information:
Valuable discussions with Prof. H. Rabitz, Prof. P. Saalfrank, Dr. T. Klamroth, and Dr. I. Andrianov are gratefully acknowledged. We also thank Prof. I. Kusunoki, Prof. T. Takaoka, Prof. T. Kometa, and Prof. J. Yoshinobu for their stimulating discussions. The author (YO) acknowledges the financial support from Tokuyama Science Foundation and a Grant-in-Aid for Scientific Research on Priority Areas (14050055). This work was partly supported by a Grant-in-Aid for Scientific Research on Priority Areas (11166205) and by the Development of High-Density Optical Pulse Generation and Advanced Material Control Techniques. Ab initio molecular orbital calculation was carried out by the Gaussian 98 package in Information Synergy Center, Tohoku University.
PY - 2002/7/3
Y1 - 2002/7/3
N2 - A hybrid quantum control scheme that combines incoherent excitation processes with coherent excitation processes in desorption induced by multiple electronic transitions (DIMET) is proposed on the basis of optimal control theory. The desorption is induced by hot electrons (incoherent excitation), while the initial configuration and/or kinetic energy of the adsorbate complex is coherently controlled by optimal IR pulses. To show its effectiveness, the results of application of this hybrid control to a 'toy model' representing DIMET of NO/Pt(111) are presented by solving the pulse design equations under the influence of strong dissipation.
AB - A hybrid quantum control scheme that combines incoherent excitation processes with coherent excitation processes in desorption induced by multiple electronic transitions (DIMET) is proposed on the basis of optimal control theory. The desorption is induced by hot electrons (incoherent excitation), while the initial configuration and/or kinetic energy of the adsorbate complex is coherently controlled by optimal IR pulses. To show its effectiveness, the results of application of this hybrid control to a 'toy model' representing DIMET of NO/Pt(111) are presented by solving the pulse design equations under the influence of strong dissipation.
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U2 - 10.1016/S0009-2614(02)00770-4
DO - 10.1016/S0009-2614(02)00770-4
M3 - Article
AN - SCOPUS:0037014728
SN - 0009-2614
VL - 360
SP - 91
EP - 98
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-2
ER -