Hydrogen-bonding ionophores for inorganic anions and nucleotides and their application in chemical sensors

Philippe Bühlmann; Shigeru Amemiya; Seiichi Nishizawa; Kang Ping Xiao; Yoshio Umezawa

doi:10.1023/a:1008055225528

Hydrogen-bonding ionophores for inorganic anions and nucleotides and their application in chemical sensors

Philippe Bühlmann, Shigeru Amemiya, Seiichi Nishizawa, Kang Ping Xiao, Yoshio Umezawa

SCI - Chemistry

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The potential and limits of hydrogen-bonding ionophores and their use in chemical sensors are discussed. Several hydrogen-bonding bis-thiourea ionophores have been found to complex inorganic anions, among them most strongly H₂PO^-₄. Using such ionophores, ion-selective electrodes for chloride and sulfate have been developed. Furthermore, hosts that bind nucleotides with up to five hydrogen bonds have been synthesized. They have been applied in nucleotide selective electrodes, optodes and voltammetric sensors mimicking ion channels.

Original language	English
Pages (from-to)	151-163
Number of pages	13
Journal	Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume	32
Issue number	2-3
DOIs	https://doi.org/10.1023/a:1008055225528
Publication status	Published - 1998 Nov

Keywords

Anion
Hydrogen bond
Ion-selective electrode
Nucleotide
Optode
Thiourea
Voltammetric sensor

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abstract = "The potential and limits of hydrogen-bonding ionophores and their use in chemical sensors are discussed. Several hydrogen-bonding bis-thiourea ionophores have been found to complex inorganic anions, among them most strongly H2PO-4. Using such ionophores, ion-selective electrodes for chloride and sulfate have been developed. Furthermore, hosts that bind nucleotides with up to five hydrogen bonds have been synthesized. They have been applied in nucleotide selective electrodes, optodes and voltammetric sensors mimicking ion channels.",

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AU - Amemiya, Shigeru

AU - Nishizawa, Seiichi

AU - Xiao, Kang Ping

AU - Umezawa, Yoshio

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AB - The potential and limits of hydrogen-bonding ionophores and their use in chemical sensors are discussed. Several hydrogen-bonding bis-thiourea ionophores have been found to complex inorganic anions, among them most strongly H2PO-4. Using such ionophores, ion-selective electrodes for chloride and sulfate have been developed. Furthermore, hosts that bind nucleotides with up to five hydrogen bonds have been synthesized. They have been applied in nucleotide selective electrodes, optodes and voltammetric sensors mimicking ion channels.

KW - Anion

KW - Hydrogen bond

KW - Ion-selective electrode

KW - Nucleotide

KW - Optode

KW - Thiourea

KW - Voltammetric sensor

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Hydrogen-bonding ionophores for inorganic anions and nucleotides and their application in chemical sensors

Abstract

Keywords

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