Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate)

Guifeng Li; Shen Ye; Shigeaki Morita; Takuma Nishida; Masatoshi Osawa

doi:10.1021/ja046183x

Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate)

Guifeng Li, Shen Ye, Shigeaki Morita, Takuma Nishida, Masatoshi Osawa

SCI - Chemistry

Hokkaido University

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.

Original language	English
Pages (from-to)	12198-12199
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	39
DOIs	https://doi.org/10.1021/ja046183x
Publication status	Published - 2004 Oct 6

Access to Document

10.1021/ja046183x

Cite this

@article{eea930870f3c4d20b0241b9cfc8c1547,

title = "Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate)",

abstract = "Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.",

author = "Guifeng Li and Shen Ye and Shigeaki Morita and Takuma Nishida and Masatoshi Osawa",

year = "2004",

month = oct,

day = "6",

doi = "10.1021/ja046183x",

language = "English",

volume = "126",

pages = "12198--12199",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "39",

}

TY - JOUR

T1 - Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate)

AU - Li, Guifeng

AU - Ye, Shen

AU - Morita, Shigeaki

AU - Nishida, Takuma

AU - Osawa, Masatoshi

PY - 2004/10/6

Y1 - 2004/10/6

N2 - Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.

AB - Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.

UR - http://www.scopus.com/inward/record.url?scp=4644256139&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4644256139&partnerID=8YFLogxK

U2 - 10.1021/ja046183x

DO - 10.1021/ja046183x

M3 - Article

AN - SCOPUS:4644256139

SN - 0002-7863

VL - 126

SP - 12198

EP - 12199

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this