Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: Synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring

Hisako Hashimoto; Katsuto Komura; Takatoshi Ishizaki; Yuto Odagiri; Hiromi Tobita

doi:10.1039/c7dt00505a

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: Synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring

Hisako Hashimoto, Katsuto Komura, Takatoshi Ishizaki, Yuto Odagiri, Hiromi Tobita

Tohoku University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M-Si-H-Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

Original language	English
Pages (from-to)	8701-8704
Number of pages	4
Journal	Dalton Transactions
Volume	46
Issue number	27
DOIs	https://doi.org/10.1039/c7dt00505a
Publication status	Published - 2017

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AU - Hashimoto, Hisako

AU - Komura, Katsuto

AU - Ishizaki, Takatoshi

AU - Odagiri, Yuto

AU - Tobita, Hiromi

N1 - Publisher Copyright: © The Royal Society of Chemistry 2017.

PY - 2017

Y1 - 2017

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AB - Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M-Si-H-Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

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Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: Synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring

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