TY - JOUR
T1 - Hydrogen production from methane by using composite-type oxygen permeable membranes
AU - Takamura, Hitoshi
AU - Ogawa, Masayuki
AU - Aizumi, Yusuke
AU - Kamegawa, Atsunori
AU - Okada, Masuo
PY - 2006
Y1 - 2006
N2 - This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO2 - 15 vol% MnFe2O 4 composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH 4 conversion, CO and H2 selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm2 s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.
AB - This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO2 - 15 vol% MnFe2O 4 composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH 4 conversion, CO and H2 selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm2 s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.
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M3 - Conference article
AN - SCOPUS:33747333922
SN - 0272-9172
VL - 885
SP - 117
EP - 121
JO - Materials Research Society Symposium Proceedings
JF - Materials Research Society Symposium Proceedings
T2 - 2005 MRS Fall Meeting
Y2 - 28 November 2005 through 1 December 2005
ER -
