Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Eunsang Kwon; Kenkichi Sakamoto; Chizuko Kabuto; Mitsuo Kira

doi:10.1246/cl.2000.1416

Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Eunsang Kwon, Kenkichi Sakamoto, Chizuko Kabuto, Mitsuo Kira

SCI - Research and Analytical Center for Giant Molecules

Tohoku University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diynes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydrazide in diglyme. The present method was applicable to the synthesis of saturated 12-and 18-membered oligosilacycloalkanes.

Original language	English
Pages (from-to)	1416-1417
Number of pages	2
Journal	Chemistry Letters
Issue number	12
DOIs	https://doi.org/10.1246/cl.2000.1416
Publication status	Published - 2000

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abstract = "The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diynes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydrazide in diglyme. The present method was applicable to the synthesis of saturated 12-and 18-membered oligosilacycloalkanes.",

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AU - Kira, Mitsuo

PY - 2000

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AB - The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diynes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydrazide in diglyme. The present method was applicable to the synthesis of saturated 12-and 18-membered oligosilacycloalkanes.

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Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Abstract

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