Improved Syntheses of (+)-Iridomyrmecin and (-)-Isoiridomyrmecin, Major Components of Matatabilactone

Masaatsu Adachi; Yu Miyazawa; Toshio Nishikawa

doi:10.1177/1934578x1601100704

Improved Syntheses of (+)-Iridomyrmecin and (-)-Isoiridomyrmecin, Major Components of Matatabilactone

Masaatsu Adachi, Yu Miyazawa, Toshio Nishikawa

PHA - Molecular Pharmaceutical Science

Nagoya University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Improved syntheses of iridomyrmecin and isoiridomyrmecin, major components of matatabilactone, are described. The synthesis features a direct transformation of nepetalactol into key intermediates by DIBAL-H reduction and provides an expeditious and straightforward production of iridoid lactones for biological investigations of the Matatabi phenomenon.

Original language	English
Pages (from-to)	883-886
Number of pages	4
Journal	Natural Product Communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1177/1934578x1601100704
Publication status	Published - 2016 Jul

Keywords

Iridoid
Iridomyrmecin
Isoiridomyrmecin
Matatabilactone

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10.1177/1934578x1601100704

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abstract = "Improved syntheses of iridomyrmecin and isoiridomyrmecin, major components of matatabilactone, are described. The synthesis features a direct transformation of nepetalactol into key intermediates by DIBAL-H reduction and provides an expeditious and straightforward production of iridoid lactones for biological investigations of the Matatabi phenomenon.",

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AU - Miyazawa, Yu

AU - Nishikawa, Toshio

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AB - Improved syntheses of iridomyrmecin and isoiridomyrmecin, major components of matatabilactone, are described. The synthesis features a direct transformation of nepetalactol into key intermediates by DIBAL-H reduction and provides an expeditious and straightforward production of iridoid lactones for biological investigations of the Matatabi phenomenon.

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KW - Isoiridomyrmecin

KW - Matatabilactone

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Improved Syntheses of (+)-Iridomyrmecin and (-)-Isoiridomyrmecin, Major Components of Matatabilactone

Abstract

Keywords

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