Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy

Shun Fujieda; A. Yoshino; K. Shinoda; S. Tsuri; S. Suzuki

doi:10.1016/j.corsci.2014.01.003

Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy

Shun Fujieda, A. Yoshino, K. Shinoda, S. Tsuri, S. Suzuki

Division of Inorganic Material Research

Research output: Contribution to journal › Article › peer-review

Abstract

Influence of tungstate ions on the transformation of chloride-containing green rust (GR(Cl^-)) to fine goethite (α-FeOOH) particles due to the oxidation reaction via aqueous solution at about 300K was investigated by in situ measurements of X-ray absorption spectra. Results showed that the transformation rate of GR(Cl^-) in the suspension containing 5mol% W was lower than that in the suspension without tungstate ions. Almost all tungstate ions in the suspension were adsorbed on GR(Cl^-) and α-FeOOH. It is probable that the adsorption of tungstate ions reduces the transformation rate of GR(Cl^-) and also leads to the precipitation of fine particles.

Original language	English
Pages (from-to)	85-92
Number of pages	8
Journal	Corrosion Science
Volume	82
DOIs	https://doi.org/10.1016/j.corsci.2014.01.003
Publication status	Published - 2014 May

Keywords

A. iron
B. EXAFS
B. XANES
C. oxidation

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Science(all)

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10.1016/j.corsci.2014.01.003

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@article{3c932c02abc249f3b8d99af7d99d7328,

title = "Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy",

abstract = "Influence of tungstate ions on the transformation of chloride-containing green rust (GR(Cl-)) to fine goethite (α-FeOOH) particles due to the oxidation reaction via aqueous solution at about 300K was investigated by in situ measurements of X-ray absorption spectra. Results showed that the transformation rate of GR(Cl-) in the suspension containing 5mol% W was lower than that in the suspension without tungstate ions. Almost all tungstate ions in the suspension were adsorbed on GR(Cl-) and α-FeOOH. It is probable that the adsorption of tungstate ions reduces the transformation rate of GR(Cl-) and also leads to the precipitation of fine particles.",

keywords = "A. iron, B. EXAFS, B. XANES, C. oxidation",

author = "Shun Fujieda and A. Yoshino and K. Shinoda and S. Tsuri and S. Suzuki",

note = "Funding Information: This research was partially supported by Grants-in-Aid for Scientific Research Fund from the Japan Society for Promotion of Science (Nos. 23360276 and 25709055). This work was performed with the approval of the Japan Synchrotron Radiation Research Institute (Proposal No. 2012A1403).",

year = "2014",

month = may,

doi = "10.1016/j.corsci.2014.01.003",

language = "English",

volume = "82",

pages = "85--92",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy

AU - Fujieda, Shun

AU - Yoshino, A.

AU - Shinoda, K.

AU - Tsuri, S.

AU - Suzuki, S.

N1 - Funding Information: This research was partially supported by Grants-in-Aid for Scientific Research Fund from the Japan Society for Promotion of Science (Nos. 23360276 and 25709055). This work was performed with the approval of the Japan Synchrotron Radiation Research Institute (Proposal No. 2012A1403).

PY - 2014/5

Y1 - 2014/5

N2 - Influence of tungstate ions on the transformation of chloride-containing green rust (GR(Cl-)) to fine goethite (α-FeOOH) particles due to the oxidation reaction via aqueous solution at about 300K was investigated by in situ measurements of X-ray absorption spectra. Results showed that the transformation rate of GR(Cl-) in the suspension containing 5mol% W was lower than that in the suspension without tungstate ions. Almost all tungstate ions in the suspension were adsorbed on GR(Cl-) and α-FeOOH. It is probable that the adsorption of tungstate ions reduces the transformation rate of GR(Cl-) and also leads to the precipitation of fine particles.

AB - Influence of tungstate ions on the transformation of chloride-containing green rust (GR(Cl-)) to fine goethite (α-FeOOH) particles due to the oxidation reaction via aqueous solution at about 300K was investigated by in situ measurements of X-ray absorption spectra. Results showed that the transformation rate of GR(Cl-) in the suspension containing 5mol% W was lower than that in the suspension without tungstate ions. Almost all tungstate ions in the suspension were adsorbed on GR(Cl-) and α-FeOOH. It is probable that the adsorption of tungstate ions reduces the transformation rate of GR(Cl-) and also leads to the precipitation of fine particles.

KW - A. iron

KW - B. EXAFS

KW - B. XANES

KW - C. oxidation

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U2 - 10.1016/j.corsci.2014.01.003

DO - 10.1016/j.corsci.2014.01.003

M3 - Article

AN - SCOPUS:84894856017

SN - 0010-938X

VL - 82

SP - 85

EP - 92

JO - Corrosion Science

JF - Corrosion Science

ER -

Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy

Abstract

Keywords

ASJC Scopus subject areas

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