TY - JOUR
T1 - Infrared and electronic spectroscopy of a model system for the nucleophilic substitution intermediate in the gas phase
T2 - The C-N valence bond formation in the benzene-ammonia cluster cation
AU - Mizuse, Kenta
AU - Fujii, Asuka
AU - Mikami, Naohiko
PY - 2006/5/25
Y1 - 2006/5/25
N2 - Infrared and electronic spectroscopy was applied to the benzene-ammonia cluster cation in the gas phase, and the observed spectra revealed the formation of a new C-N valence bond between the benzene and ammonia moieties, which has been predicted by the quantum chemical calculations (Tachikawa, H. Phys. Chem. Chem. Phys. 2002, 4, 6018). This cluster cation is regarded as a model for the cyclohexadienyl type intermediate in nucleophilic substitution reactions.
AB - Infrared and electronic spectroscopy was applied to the benzene-ammonia cluster cation in the gas phase, and the observed spectra revealed the formation of a new C-N valence bond between the benzene and ammonia moieties, which has been predicted by the quantum chemical calculations (Tachikawa, H. Phys. Chem. Chem. Phys. 2002, 4, 6018). This cluster cation is regarded as a model for the cyclohexadienyl type intermediate in nucleophilic substitution reactions.
UR - http://www.scopus.com/inward/record.url?scp=33745775711&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33745775711&partnerID=8YFLogxK
U2 - 10.1021/jp061028l
DO - 10.1021/jp061028l
M3 - Article
AN - SCOPUS:33745775711
SN - 1089-5639
VL - 110
SP - 6387
EP - 6390
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
IS - 20
ER -