Infrared dissociation spectroscopy of the OH stretching vibration of phenol-rare gas van der Waals cluster ions

Asuka Fujii; Takahiro Sawamura; Shigeki Tanabe; Takayuki Ebata; Naohiko Mikami

doi:10.1016/0009-2614(94)00616-4

Infrared dissociation spectroscopy of the OH stretching vibration of phenol-rare gas van der Waals cluster ions

Asuka Fujii, Takahiro Sawamura, Shigeki Tanabe, Takayuki Ebata, Naohiko Mikami

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

Infrared dissociation spectra of phenol-Ar and -Kr van der Waals cluster ions in supersonic free jets were observed in the absorption region of the OH stretching vibration. Both spectra showed the OH stretching vibration at 3535 ± 2 cm^-1, indicating that the perturbation of the rare gases is small and the observed frequency represents that of the bare phenol ion. The vibrational frequency of the phenol ion was found to be 122 cm^- smaller than that of neutral phenol.

Original language	English
Pages (from-to)	104-107
Number of pages	4
Journal	Chemical Physics Letters
Volume	225
Issue number	1-3
DOIs	https://doi.org/10.1016/0009-2614(94)00616-4
Publication status	Published - 1994 Jul 29

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abstract = "Infrared dissociation spectra of phenol-Ar and -Kr van der Waals cluster ions in supersonic free jets were observed in the absorption region of the OH stretching vibration. Both spectra showed the OH stretching vibration at 3535 ± 2 cm-1, indicating that the perturbation of the rare gases is small and the observed frequency represents that of the bare phenol ion. The vibrational frequency of the phenol ion was found to be 122 cm- smaller than that of neutral phenol.",

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AU - Fujii, Asuka

AU - Sawamura, Takahiro

AU - Tanabe, Shigeki

AU - Ebata, Takayuki

AU - Mikami, Naohiko

PY - 1994/7/29

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AB - Infrared dissociation spectra of phenol-Ar and -Kr van der Waals cluster ions in supersonic free jets were observed in the absorption region of the OH stretching vibration. Both spectra showed the OH stretching vibration at 3535 ± 2 cm-1, indicating that the perturbation of the rare gases is small and the observed frequency represents that of the bare phenol ion. The vibrational frequency of the phenol ion was found to be 122 cm- smaller than that of neutral phenol.

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Infrared dissociation spectroscopy of the OH stretching vibration of phenol-rare gas van der Waals cluster ions

Abstract

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