Infrared spectroscopic study on the dye containing LB films

Yoshiaki Hirano; Shin Ichi Morita; Yasuhiro F. Miura; Michio Sugi

doi:10.1016/S0040-6090(03)00776-4

Infrared spectroscopic study on the dye containing LB films

Yoshiaki Hirano, Shin Ichi Morita, Yasuhiro F. Miura, Michio Sugi

SCI - Chemistry

Toin University of Yokohama

Research output: Contribution to journal › Conference article › peer-review

5 Citations (Scopus)

Abstract

We have studied the structures of the blue-shifted H- and the red-shifted J-bands formed in the mixed Langmuir-Blodgett (LB) films of the merocyanine dye (MS)-arachidic acid (C₂₀)-n-octadecane (AL₁₈) with the molar mixing ratio [MS]:[C₂₀]:[AL₁₈]=1:2:x (0≦x≦5). The mobility of the alkyl chain of MS has been investigated as a function of the molar mixing ratio x by means of infrared spectroscopy. The results have indicated that the J-aggregate is accompanied by the thermal motion of the alkyl chain of MS, while the H-aggregate is accompanied by the highly packed state of the alkyl chains of MS and deuterated AL₁₈ (AL ₁₈-d).

Original language	English
Pages (from-to)	225-229
Number of pages	5
Journal	Thin Solid Films
Volume	438-439
DOIs	https://doi.org/10.1016/S0040-6090(03)00776-4
Publication status	Published - 2003 Aug 22
Event	The 5th International Conference on Nano-Molecular Electronics - Kobe, Japan Duration: 2002 Dec 10 → 2002 Dec 12

Keywords

H-aggregate
Infrared spectroscopy
LB films
Merocyanine dye
Ternary system
Thermal mobility

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10.1016/S0040-6090(03)00776-4

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@article{3841e10edf1a4c7481c53cb2a528d5cb,

title = "Infrared spectroscopic study on the dye containing LB films",

abstract = "We have studied the structures of the blue-shifted H- and the red-shifted J-bands formed in the mixed Langmuir-Blodgett (LB) films of the merocyanine dye (MS)-arachidic acid (C20)-n-octadecane (AL18) with the molar mixing ratio [MS]:[C20]:[AL18]=1:2:x (0≦x≦5). The mobility of the alkyl chain of MS has been investigated as a function of the molar mixing ratio x by means of infrared spectroscopy. The results have indicated that the J-aggregate is accompanied by the thermal motion of the alkyl chain of MS, while the H-aggregate is accompanied by the highly packed state of the alkyl chains of MS and deuterated AL18 (AL 18-d).",

keywords = "H-aggregate, Infrared spectroscopy, LB films, Merocyanine dye, Ternary system, Thermal mobility",

author = "Yoshiaki Hirano and Morita, {Shin Ichi} and Miura, {Yasuhiro F.} and Michio Sugi",

year = "2003",

month = aug,

day = "22",

doi = "10.1016/S0040-6090(03)00776-4",

language = "English",

volume = "438-439",

pages = "225--229",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier",

note = "The 5th International Conference on Nano-Molecular Electronics ; Conference date: 10-12-2002 Through 12-12-2002",

}

TY - JOUR

T1 - Infrared spectroscopic study on the dye containing LB films

AU - Hirano, Yoshiaki

AU - Morita, Shin Ichi

AU - Miura, Yasuhiro F.

AU - Sugi, Michio

PY - 2003/8/22

Y1 - 2003/8/22

N2 - We have studied the structures of the blue-shifted H- and the red-shifted J-bands formed in the mixed Langmuir-Blodgett (LB) films of the merocyanine dye (MS)-arachidic acid (C20)-n-octadecane (AL18) with the molar mixing ratio [MS]:[C20]:[AL18]=1:2:x (0≦x≦5). The mobility of the alkyl chain of MS has been investigated as a function of the molar mixing ratio x by means of infrared spectroscopy. The results have indicated that the J-aggregate is accompanied by the thermal motion of the alkyl chain of MS, while the H-aggregate is accompanied by the highly packed state of the alkyl chains of MS and deuterated AL18 (AL 18-d).

AB - We have studied the structures of the blue-shifted H- and the red-shifted J-bands formed in the mixed Langmuir-Blodgett (LB) films of the merocyanine dye (MS)-arachidic acid (C20)-n-octadecane (AL18) with the molar mixing ratio [MS]:[C20]:[AL18]=1:2:x (0≦x≦5). The mobility of the alkyl chain of MS has been investigated as a function of the molar mixing ratio x by means of infrared spectroscopy. The results have indicated that the J-aggregate is accompanied by the thermal motion of the alkyl chain of MS, while the H-aggregate is accompanied by the highly packed state of the alkyl chains of MS and deuterated AL18 (AL 18-d).

KW - H-aggregate

KW - Infrared spectroscopy

KW - LB films

KW - Merocyanine dye

KW - Ternary system

KW - Thermal mobility

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UR - http://www.scopus.com/inward/citedby.url?scp=17344395227&partnerID=8YFLogxK

U2 - 10.1016/S0040-6090(03)00776-4

DO - 10.1016/S0040-6090(03)00776-4

M3 - Conference article

AN - SCOPUS:17344395227

SN - 0040-6090

VL - 438-439

SP - 225

EP - 229

JO - Thin Solid Films

JF - Thin Solid Films

T2 - The 5th International Conference on Nano-Molecular Electronics

Y2 - 10 December 2002 through 12 December 2002

ER -

Infrared spectroscopic study on the dye containing LB films

Abstract

Keywords

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