Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60·−

Hiroshi Ueno; Ken Kokubo; Yuji Nakamura; Kei Ohkubo; Naohiko Ikuma; Hiroshi Moriyama; Shunichi Fukuzumi; Takumi Oshimaa

doi:10.1039/c3cc43901a

Ionic conductivity of [Li⁺@C₆₀](PF₆⁻) in organic solvents and its electrochemical reduction to Li⁺@C₆₀·⁻

Hiroshi Ueno, Ken Kokubo, Yuji Nakamura, Kei Ohkubo, Naohiko Ikuma, Hiroshi Moriyama, Shunichi Fukuzumi, Takumi Oshimaa

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The ionic conductivity of [Li⁺@C₆₀](PF₆⁻) was measured in o-dichlorobenzene, and found to be higher than that of TBA⁺PF₆⁻. Electrochemical reduction of [Li⁺@C₆₀](PF₆⁻) without any supporting electrolyte gave the monovalent radical anion Li⁺@C₆₀·⁻, as confirmed by the characteristic ESR signal and NIR absorption band.

Original language	English
Pages (from-to)	7376-7378
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	67
DOIs	https://doi.org/10.1039/c3cc43901a
Publication status	Published - 2013 Jul 25
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc43901a

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title = "Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60·−",

abstract = "The ionic conductivity of [Li+@C60](PF6−) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6−. Electrochemical reduction of [Li+@C60](PF6−) without any supporting electrolyte gave the monovalent radical anion Li+@C60·−, as confirmed by the characteristic ESR signal and NIR absorption band.",

author = "Hiroshi Ueno and Ken Kokubo and Yuji Nakamura and Kei Ohkubo and Naohiko Ikuma and Hiroshi Moriyama and Shunichi Fukuzumi and Takumi Oshimaa",

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language = "English",

volume = "49",

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T1 - Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60·−

AU - Ueno, Hiroshi

AU - Kokubo, Ken

AU - Nakamura, Yuji

AU - Ohkubo, Kei

AU - Ikuma, Naohiko

AU - Moriyama, Hiroshi

AU - Fukuzumi, Shunichi

AU - Oshimaa, Takumi

PY - 2013/7/25

Y1 - 2013/7/25

N2 - The ionic conductivity of [Li+@C60](PF6−) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6−. Electrochemical reduction of [Li+@C60](PF6−) without any supporting electrolyte gave the monovalent radical anion Li+@C60·−, as confirmed by the characteristic ESR signal and NIR absorption band.

AB - The ionic conductivity of [Li+@C60](PF6−) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6−. Electrochemical reduction of [Li+@C60](PF6−) without any supporting electrolyte gave the monovalent radical anion Li+@C60·−, as confirmed by the characteristic ESR signal and NIR absorption band.

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Ionic conductivity of [Li⁺@C₆₀](PF₆⁻) in organic solvents and its electrochemical reduction to Li⁺@C₆₀·⁻

Abstract

ASJC Scopus subject areas

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