@article{5c373ebd1e554f608f33f3f8edccece7,
title = "Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C-H borylation of arenes",
abstract = "Unsaturated 16-electron iridium and rhodium complexes bearing a silyl-bipyridine-based SiNN-pincer ligand (BpySiNN) were synthesised and characterised by X-ray crystallography and NMR spectroscopy. The iridium-BpySiNN complex facilitated the catalytic C(sp2)-H borylation of arenes to give arylboronate esters in high yields (≥93%) under mild conditions (∼40 °C).",
author = "Takashi Komuro and Daiki Mochizuki and Hisako Hashimoto and Hiromi Tobita",
note = "Funding Information: This work was supported by JSPS KAKENHI Grants JP19K05490, JP16K05714 and JP15H03782 from the Japan Society for the Promotion of Science (JSPS). We are also grateful to the Research and Analytical Center for Giant Molecules, Tohoku University, for mass spectroscopic measurements and elemental analysis. Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",
year = "2022",
month = jun,
day = "13",
doi = "10.1039/d2dt01227h",
language = "English",
volume = "51",
pages = "9983--9987",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "26",
}