Iron-Catalyzed C−C Bond Formation via Chelation-Assisted C−H Activation

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Abstract

This review provides a brief overview of iron-catalyzed C−C bond forming reactions via heteroatom-assisted C−H bond activation, which have been extensively developed in the last decade. Three major types of reactions are discussed, namely, (1) C−H activation/C−C coupling using organometallic reagents under oxidative conditions, (2) C−H activation/C−C coupling using organic electrophiles under redox-neutral conditions, and (3) C−H activation/C−C coupling using unsaturated hydrocarbons under redox-neutral or oxidative conditions.

Original languageEnglish
Pages (from-to)1117-1130
Number of pages14
JournalIsrael Journal of Chemistry
Volume57
Issue number12
DOIs
Publication statusPublished - 2017 Dec

Keywords

  • cross-coupling
  • C−C bond formation
  • C−H activation
  • iron
  • organometallic chemistry

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