Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents

Laurean Ilies; Jun Okabe; Naohiko Yoshikai; Eiichi Nakamura

doi:10.1021/ol1009448

Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents

Laurean Ilies, Jun Okabe, Naohiko Yoshikai, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

(Figure presented) Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.

Original language	English
Pages (from-to)	2838-2840
Number of pages	3
Journal	Organic letters
Volume	12
Issue number	12
DOIs	https://doi.org/10.1021/ol1009448
Publication status	Published - 2010 Jun 18
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol1009448

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title = "Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents",

abstract = "(Figure presented) Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.",

author = "Laurean Ilies and Jun Okabe and Naohiko Yoshikai and Eiichi Nakamura",

year = "2010",

month = jun,

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doi = "10.1021/ol1009448",

language = "English",

volume = "12",

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journal = "Organic Letters",

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T1 - Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents

AU - Ilies, Laurean

AU - Okabe, Jun

AU - Yoshikai, Naohiko

AU - Nakamura, Eiichi

PY - 2010/6/18

Y1 - 2010/6/18

N2 - (Figure presented) Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.

AB - (Figure presented) Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.

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U2 - 10.1021/ol1009448

DO - 10.1021/ol1009448

M3 - Article

C2 - 20499852

AN - SCOPUS:77953546363

SN - 1523-7060

VL - 12

SP - 2838

EP - 2840

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents

Abstract

ASJC Scopus subject areas

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