Kinetic gate-opening process in a flexible porous coordination polymer

Daisuke Tanaka; Keiji Nakagawa; Masakazu Higuchi; Satoshi Horike; Yoshiki Kubota; Tatsuo C. Kobayashi; Masaki Takata; Susumu Kitagawa

doi:10.1002/anie.200705822

Kinetic gate-opening process in a flexible porous coordination polymer

Daisuke Tanaka, Keiji Nakagawa, Masakazu Higuchi, Satoshi Horike, Yoshiki Kubota, Tatsuo C. Kobayashi, Masaki Takata, Susumu Kitagawa

SRIS - SR Core Research Division

Research output: Contribution to journal › Article › peer-review

281 Citations (Scopus)

Abstract

(Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.

Original language	English
Pages (from-to)	3914-3918
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	21
DOIs	https://doi.org/10.1002/anie.200705822
Publication status	Published - 2008 May 13

Keywords

Adsorption
Coordination polymers
Kinetics
Microporous materials
Phase transition

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10.1002/anie.200705822

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abstract = "(Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.",

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AU - Tanaka, Daisuke

AU - Nakagawa, Keiji

AU - Higuchi, Masakazu

AU - Horike, Satoshi

AU - Kubota, Yoshiki

AU - Kobayashi, Tatsuo C.

AU - Takata, Masaki

AU - Kitagawa, Susumu

PY - 2008/5/13

Y1 - 2008/5/13

N2 - (Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.

AB - (Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.

KW - Adsorption

KW - Coordination polymers

KW - Kinetics

KW - Microporous materials

KW - Phase transition

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JF - Angewandte Chemie - International Edition

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Kinetic gate-opening process in a flexible porous coordination polymer

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Keywords

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