Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η5-C5H4(SiMe3)} 4Fe4S6

Hiromi Tobita; Mikiya Yamada; Shinji Inomata; Hiroshi Ogino

doi:10.1246/cl.1998.507

Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η⁵-C₅H₄(SiMe₃)} ₄Fe₄S₆

Hiromi Tobita, Mikiya Yamada, Shinji Inomata, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A chiral cluster Cp^S1₄Fe₄S₆ (Cp^S1 = η⁵-C₅H₄(SiMe₃)) was found to be fluxional due to the skeletal inversion. The line shape analysis for variable temperature ¹H NMR spectra (400 MHz, toluene-d₈) yielded activation parameters: ΔH ‡ = 63.7 ± 16.0 kJ mol^-1 and ΔS ‡ = -20.8 ± 16.0 J mol^-1 K_-1. A plausible mechanism for the dynamic behavior is proposed.

Original language	English
Pages (from-to)	507-508
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.1998.507
Publication status	Published - 1998

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10.1246/cl.1998.507

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title = "Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η5-C5H4(SiMe3)} 4Fe4S6",

abstract = "A chiral cluster CpS14Fe4S6 (CpS1 = η5-C5H4(SiMe3)) was found to be fluxional due to the skeletal inversion. The line shape analysis for variable temperature 1H NMR spectra (400 MHz, toluene-d8) yielded activation parameters: ΔH ‡ = 63.7 ± 16.0 kJ mol-1 and ΔS ‡ = -20.8 ± 16.0 J mol-1 K-1. A plausible mechanism for the dynamic behavior is proposed.",

author = "Hiromi Tobita and Mikiya Yamada and Shinji Inomata and Hiroshi Ogino",

year = "1998",

doi = "10.1246/cl.1998.507",

language = "English",

pages = "507--508",

journal = "Chemistry Letters",

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T1 - Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η5-C5H4(SiMe3)} 4Fe4S6

AU - Tobita, Hiromi

AU - Yamada, Mikiya

AU - Inomata, Shinji

AU - Ogino, Hiroshi

PY - 1998

Y1 - 1998

N2 - A chiral cluster CpS14Fe4S6 (CpS1 = η5-C5H4(SiMe3)) was found to be fluxional due to the skeletal inversion. The line shape analysis for variable temperature 1H NMR spectra (400 MHz, toluene-d8) yielded activation parameters: ΔH ‡ = 63.7 ± 16.0 kJ mol-1 and ΔS ‡ = -20.8 ± 16.0 J mol-1 K-1. A plausible mechanism for the dynamic behavior is proposed.

AB - A chiral cluster CpS14Fe4S6 (CpS1 = η5-C5H4(SiMe3)) was found to be fluxional due to the skeletal inversion. The line shape analysis for variable temperature 1H NMR spectra (400 MHz, toluene-d8) yielded activation parameters: ΔH ‡ = 63.7 ± 16.0 kJ mol-1 and ΔS ‡ = -20.8 ± 16.0 J mol-1 K-1. A plausible mechanism for the dynamic behavior is proposed.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η⁵-C₅H₄(SiMe₃)} ₄Fe₄S₆

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