Abstract
A series of experiments for measurement of non-catalytic water-gas shift reaction rate was carried out in supercritical water at 380°-440°C and 10-30 MPa using a flow-type apparatus. At 380°C, the reaction rate gradually decreased to a minimum at around the critical point, and then increased with increasing water density. However, at 400°C, the reaction rate order was zero with respect to water density. The rate constant for the water-gas shift reaction was compared with a global reaction model, which can reproduce the experimental data of CO conversion. Original is an abstract.
| Original language | English |
|---|---|
| Number of pages | 1 |
| Journal | JOURNAL of CHEMICAL ENGINEERING of JAPAN |
| Volume | 32 |
| Issue number | 6 |
| Publication status | Published - 1999 Dec 1 |
Keywords
- CO-water
- Supercritical water
- Water-gas shift reaction
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)