Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

Qiong Ye; Hong Zhao; Zhi Rong Qu; Da Wei Fu; Ren Gen Xiong; Yi Ping Cui; Tomoyuki Akutagawa; Philip Wai Hong Chan; Takayoshi Nakamura

doi:10.1002/anie.200700629

Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

Qiong Ye, Hong Zhao, Zhi Rong Qu, Da Wei Fu, Ren Gen Xiong, Yi Ping Cui, Tomoyuki Akutagawa, Philip Wai Hong Chan, Takayoshi Nakamura

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

(Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal.

Original language	English
Pages (from-to)	6852-6856
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	36
DOIs	https://doi.org/10.1002/anie.200700629
Publication status	Published - 2007

Keywords

Copper
Deuterium
Dielectric constant
Isotopic effects
X-ray diffraction

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10.1002/anie.200700629

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title = "Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex",

abstract = "(Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal.",

keywords = "Copper, Deuterium, Dielectric constant, Isotopic effects, X-ray diffraction",

author = "Qiong Ye and Hong Zhao and Qu, {Zhi Rong} and Fu, {Da Wei} and Xiong, {Ren Gen} and Cui, {Yi Ping} and Tomoyuki Akutagawa and Chan, {Philip Wai Hong} and Takayoshi Nakamura",

year = "2007",

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journal = "Angewandte Chemie - International Edition",

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T1 - Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

AU - Ye, Qiong

AU - Zhao, Hong

AU - Qu, Zhi Rong

AU - Fu, Da Wei

AU - Xiong, Ren Gen

AU - Cui, Yi Ping

AU - Akutagawa, Tomoyuki

AU - Chan, Philip Wai Hong

AU - Nakamura, Takayoshi

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal.

AB - (Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal.

KW - Copper

KW - Deuterium

KW - Dielectric constant

KW - Isotopic effects

KW - X-ray diffraction

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U2 - 10.1002/anie.200700629

DO - 10.1002/anie.200700629

M3 - Article

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JF - Angewandte Chemie - International Edition

IS - 36

ER -

Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

Abstract

Keywords

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