@article{f6d199f7c14e43fb8aa14505e9a096e2,
title = "Layering and Ordering in Electrochemical Double Layers",
abstract = "Electrochemical double layers (EDL) form at electrified interfaces. Whereas the Gouy-Chapman model describes moderately charged EDL, the formation of Stern layers was predicted for highly charged EDL. Our results provide structural evidence for a Stern layer of cations at potentials close to hydrogen evolution in alkali fluoride and chloride electrolytes. Layering was observed by X-ray crystal truncation rods and atomic-scale recoil responses of Pt(111) surface layers. Ordering in the layer was confirmed by glancing-incidence in-plane diffraction measurements.",
author = "Yihua Liu and Tomoya Kawaguchi and Pierce, {Michael S.} and Vladimir Komanicky and Hoydoo You",
note = "Funding Information: The work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Science (BES), Materials Sciences and Engineering Division and use of the APS by DOE BES Scientific User Facilities Division, under contract no. DE-AC02-06CH11357. T.K. thanks the Japanese Society for the Promotion of Science (JSPS) for JSPS Postdoctoral Fellowships for Research Abroad. The work at RIT was supported by the Research Corporation for Science Advancement (RCSA) through a Cottrell College Science. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = mar,
day = "15",
doi = "10.1021/acs.jpclett.8b00123",
language = "English",
volume = "9",
pages = "1265--1271",
journal = "Journal of Physical Chemistry Letters",
issn = "1948-7185",
publisher = "American Chemical Society",
number = "6",
}