Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr 6O 4(OH) 4(BDC) 6 (UiO-66)

Maw Lin Foo; Satoshi Horike; Tomohiro Fukushima; Yuh Hijikata; Yoshiki Kubota; Masaki Takata; Susumu Kitagawa

doi:10.1039/c2dt31195j

Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr ₆O ₄(OH) ₄(BDC) ₆ (UiO-66)

Maw Lin Foo, Satoshi Horike, Tomohiro Fukushima, Yuh Hijikata, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa

SRIS - SR Core Research Division

Research output: Contribution to journal › Article › peer-review

165 Citations (Scopus)

Abstract

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr ₆O ₄(OH) ₄(BDC-SO ₃H) _1.1(BDC) _4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr ₆O ₄(OH) ₄(BDC) ₆.

Original language	English
Pages (from-to)	13791-13794
Number of pages	4
Journal	Dalton Transactions
Volume	41
Issue number	45
DOIs	https://doi.org/10.1039/c2dt31195j
Publication status	Published - 2012 Dec 7

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title = "Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr 6O 4(OH) 4(BDC) 6 (UiO-66)",

abstract = "By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr 6O 4(OH) 4(BDC-SO 3H) 1.1(BDC) 4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr 6O 4(OH) 4(BDC) 6.",

author = "{Lin Foo}, Maw and Satoshi Horike and Tomohiro Fukushima and Yuh Hijikata and Yoshiki Kubota and Masaki Takata and Susumu Kitagawa",

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language = "English",

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AU - Lin Foo, Maw

AU - Horike, Satoshi

AU - Fukushima, Tomohiro

AU - Hijikata, Yuh

AU - Kubota, Yoshiki

AU - Takata, Masaki

AU - Kitagawa, Susumu

PY - 2012/12/7

Y1 - 2012/12/7

N2 - By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr 6O 4(OH) 4(BDC-SO 3H) 1.1(BDC) 4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr 6O 4(OH) 4(BDC) 6.

AB - By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr 6O 4(OH) 4(BDC-SO 3H) 1.1(BDC) 4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr 6O 4(OH) 4(BDC) 6.

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DO - 10.1039/c2dt31195j

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JF - Dalton Transactions

IS - 45

ER -

Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr ₆O ₄(OH) ₄(BDC) ₆ (UiO-66)

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