Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(ii) complex CuCl2(pdz) with a staggered g-tensor

Shinya Takaishi; Hiroshi Kitagawa; Hisaaki Tanaka; Shin Ichi Kuroda; Ryuichi Ikeda

doi:10.1039/c4dt00809j

Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(ii) complex CuCl₂(pdz) with a staggered g-tensor

Shinya Takaishi, Hiroshi Kitagawa, Hisaaki Tanaka, Shin Ichi Kuroda, Ryuichi Ikeda

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We report an unusual magnetic anisotropy in a S = 1/2 1D antiferromagnetic (AF) compound CuCl₂(pdz) (pdz = pyridazine). The magnetic susceptibility for H//a* and H//c showed characteristic behavior in the S = 1/2 1D Heisenberg AF system, whereas that for H//b exhibited a 1/T contribution. The origin of such an anomalous anisotropy in the magnetic susceptibility is explained by the staggered g-tensor of this compound. This journal is

Original language	English
Pages (from-to)	11529-11532
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	30
DOIs	https://doi.org/10.1039/c4dt00809j
Publication status	Published - 2014 Aug 14

ASJC Scopus subject areas

Inorganic Chemistry

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AU - Takaishi, Shinya

AU - Kitagawa, Hiroshi

AU - Tanaka, Hisaaki

AU - Kuroda, Shin Ichi

AU - Ikeda, Ryuichi

PY - 2014/8/14

Y1 - 2014/8/14

N2 - We report an unusual magnetic anisotropy in a S = 1/2 1D antiferromagnetic (AF) compound CuCl2(pdz) (pdz = pyridazine). The magnetic susceptibility for H//a* and H//c showed characteristic behavior in the S = 1/2 1D Heisenberg AF system, whereas that for H//b exhibited a 1/T contribution. The origin of such an anomalous anisotropy in the magnetic susceptibility is explained by the staggered g-tensor of this compound. This journal is

AB - We report an unusual magnetic anisotropy in a S = 1/2 1D antiferromagnetic (AF) compound CuCl2(pdz) (pdz = pyridazine). The magnetic susceptibility for H//a* and H//c showed characteristic behavior in the S = 1/2 1D Heisenberg AF system, whereas that for H//b exhibited a 1/T contribution. The origin of such an anomalous anisotropy in the magnetic susceptibility is explained by the staggered g-tensor of this compound. This journal is

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JF - Dalton Transactions

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Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(ii) complex CuCl₂(pdz) with a staggered g-tensor

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