Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex

Keiichi Katoh; Takashi Kajiwara; Motohiro Nakano; Yasuhiro Nakazawa; Wolfgang Wernsdorfer; Naoto Ishikawa; Brian K. Breedlove; Masahiro Yamashita

doi:10.1002/chem.201002026

Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex

Keiichi Katoh, Takashi Kajiwara, Motohiro Nakano, Yasuhiro Nakazawa, Wolfgang Wernsdorfer, Naoto Ishikawa, Brian K. Breedlove, Masahiro Yamashita

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

A single magnet in a triple decker! Tb^III-phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.

Original language	English
Pages (from-to)	117-122
Number of pages	6
Journal	Chemistry - A European Journal
Volume	17
Issue number	1
DOIs	https://doi.org/10.1002/chem.201002026
Publication status	Published - 2011 Jan 3

Keywords

lanthanoids
ligand field theory
magnetic properties
phthalocyanines
single-molecule magnets

Access to Document

10.1002/chem.201002026

Cite this

@article{761a9eeb747f4cacbad609bed5310fc8,

title = "Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex",

abstract = "A single magnet in a triple decker! TbIII-phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.",

keywords = "lanthanoids, ligand field theory, magnetic properties, phthalocyanines, single-molecule magnets",

author = "Keiichi Katoh and Takashi Kajiwara and Motohiro Nakano and Yasuhiro Nakazawa and Wolfgang Wernsdorfer and Naoto Ishikawa and Breedlove, {Brian K.} and Masahiro Yamashita",

year = "2011",

month = jan,

day = "3",

doi = "10.1002/chem.201002026",

language = "English",

volume = "17",

pages = "117--122",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - Magnetic relaxation of single-molecule magnets in an external magnetic field

T2 - An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex

AU - Katoh, Keiichi

AU - Kajiwara, Takashi

AU - Nakano, Motohiro

AU - Nakazawa, Yasuhiro

AU - Wernsdorfer, Wolfgang

AU - Ishikawa, Naoto

AU - Breedlove, Brian K.

AU - Yamashita, Masahiro

PY - 2011/1/3

Y1 - 2011/1/3

N2 - A single magnet in a triple decker! TbIII-phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.

AB - A single magnet in a triple decker! TbIII-phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.

KW - lanthanoids

KW - ligand field theory

KW - magnetic properties

KW - phthalocyanines

KW - single-molecule magnets

UR - http://www.scopus.com/inward/record.url?scp=78650984846&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78650984846&partnerID=8YFLogxK

U2 - 10.1002/chem.201002026

DO - 10.1002/chem.201002026

M3 - Article

AN - SCOPUS:78650984846

SN - 0947-6539

VL - 17

SP - 117

EP - 122

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 1

ER -

Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this