TY - GEN
T1 - Magnetoelectrodeposition for the chiral surface formation of Cu films
AU - Mogi, I.
AU - Aogaki, R.
AU - Morimoto, R.
AU - Watanabe, K.
PY - 2012
Y1 - 2012
N2 - Cu films were electrodeposited at a constant potential under a magnetic field of 5 T on the Pt disc electrodes with diameters of 3 mm ~ 25 μm. Such magnetoelectrodeposited Cu films were employed as an electrode, and cyclic voltammograms were measured for the electrochemical reactions of the enantiomers of alanine. Chiral behavior was observed in the oxidation currents between the enantiomers. The clear chiral behavior was observed on the micro-disk electrode. The galvanostatic and pulse electrodeposition of the Cu films was also conducted in the magnetic field, and the chiral behavior depended on the pulse width. These results are discussed in connection with the micro- MHD and vertical MHD convections.
AB - Cu films were electrodeposited at a constant potential under a magnetic field of 5 T on the Pt disc electrodes with diameters of 3 mm ~ 25 μm. Such magnetoelectrodeposited Cu films were employed as an electrode, and cyclic voltammograms were measured for the electrochemical reactions of the enantiomers of alanine. Chiral behavior was observed in the oxidation currents between the enantiomers. The clear chiral behavior was observed on the micro-disk electrode. The galvanostatic and pulse electrodeposition of the Cu films was also conducted in the magnetic field, and the chiral behavior depended on the pulse width. These results are discussed in connection with the micro- MHD and vertical MHD convections.
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U2 - 10.1149/04512.0001ecst
DO - 10.1149/04512.0001ecst
M3 - Conference contribution
AN - SCOPUS:84885782579
SN - 9781623320188
T3 - ECS Transactions
SP - 1
EP - 8
BT - Exploiting Magnets in Electrochemistry
PB - Electrochemical Society Inc.
T2 - Symposium on Exploiting Magnets in Electrochemistry - 221st ECS Meeting
Y2 - 6 May 2012 through 10 May 2012
ER -