Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

Satoshi Yamashita; Takuya Shiga; Masashi Kurashina; Masayuki Nihei; Hiroyuki Nojiri; Hiroshi Sawa; Toru Kakiuchi; Hiroki Oshio

doi:10.1021/ic062258h

Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

Satoshi Yamashita, Takuya Shiga, Masashi Kurashina, Masayuki Nihei, Hiroyuki Nojiri, Hiroshi Sawa, Toru Kakiuchi, Hiroki Oshio

IMR - Institute for Materials Research (institute affiliation only)

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear Cu^II complexes trapped oxo-bridged [Mn^III ₈Mn^IV₄O₁₂] and [Mn ^III₆O₆] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

Original language	English
Pages (from-to)	3810-3812
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	10
DOIs	https://doi.org/10.1021/ic062258h
Publication status	Published - 2007 May 14

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title = "Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes",

abstract = "Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII 8MnIV4O12] and [Mn III6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.",

author = "Satoshi Yamashita and Takuya Shiga and Masashi Kurashina and Masayuki Nihei and Hiroyuki Nojiri and Hiroshi Sawa and Toru Kakiuchi and Hiroki Oshio",

year = "2007",

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volume = "46",

pages = "3810--3812",

journal = "Inorganic Chemistry",

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T1 - Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

AU - Yamashita, Satoshi

AU - Shiga, Takuya

AU - Kurashina, Masashi

AU - Nihei, Masayuki

AU - Nojiri, Hiroyuki

AU - Sawa, Hiroshi

AU - Kakiuchi, Toru

AU - Oshio, Hiroki

PY - 2007/5/14

Y1 - 2007/5/14

N2 - Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII 8MnIV4O12] and [Mn III6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

AB - Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII 8MnIV4O12] and [Mn III6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

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U2 - 10.1021/ic062258h

DO - 10.1021/ic062258h

M3 - Article

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VL - 46

SP - 3810

EP - 3812

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 10

ER -

Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

Abstract

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