Metal-substituted disilynes with linear forms

Masae Takahashi; Yoshiyuki Kawazoe

doi:10.1021/om800469w

Metal-substituted disilynes with linear forms

Masae Takahashi, Yoshiyuki Kawazoe

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The present systematic survey of linear disilynes ESi≡SiE with various metal elements E by ab initio and density functional theory calculations has shown that magnesium is highly suited to stabilize the linear conformation of the Si≡Si bond. A synthetically accessible model compound using the magnesium complex of a core-modified porphyrin as a substituent has been designed.

Original language	English
Pages (from-to)	4829-4832
Number of pages	4
Journal	Organometallics
Volume	27
Issue number	19
DOIs	https://doi.org/10.1021/om800469w
Publication status	Published - 2008 Oct 13

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10.1021/om800469w

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abstract = "The present systematic survey of linear disilynes ESi≡SiE with various metal elements E by ab initio and density functional theory calculations has shown that magnesium is highly suited to stabilize the linear conformation of the Si≡Si bond. A synthetically accessible model compound using the magnesium complex of a core-modified porphyrin as a substituent has been designed.",

author = "Masae Takahashi and Yoshiyuki Kawazoe",

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AB - The present systematic survey of linear disilynes ESi≡SiE with various metal elements E by ab initio and density functional theory calculations has shown that magnesium is highly suited to stabilize the linear conformation of the Si≡Si bond. A synthetically accessible model compound using the magnesium complex of a core-modified porphyrin as a substituent has been designed.

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Metal-substituted disilynes with linear forms

Abstract

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