Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers

Ryotaro Matsuda; Wataru Kosaka; Ryo Kitaura; Yoshiki Kubota; Masaki Takata; Susumu Kitagawa

doi:10.1016/j.micromeso.2013.10.029

Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers

Ryotaro Matsuda, Wataru Kosaka, Ryo Kitaura, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.

Original language	English
Pages (from-to)	83-90
Number of pages	8
Journal	Microporous and Mesoporous Materials
Volume	189
DOIs	https://doi.org/10.1016/j.micromeso.2013.10.029
Publication status	Published - 2014 May 1
Externally published	Yes

Keywords

Adsorption
Metal-organic frameworks
Micropore
Porous coordination polymers

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics
Mechanics of Materials

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10.1016/j.micromeso.2013.10.029

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title = "Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers",

abstract = "Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.",

keywords = "Adsorption, Metal-organic frameworks, Micropore, Porous coordination polymers",

author = "Ryotaro Matsuda and Wataru Kosaka and Ryo Kitaura and Yoshiki Kubota and Masaki Takata and Susumu Kitagawa",

note = "Funding Information: The synchrotron radiation experiments were performed at the BL44B2 RIKEN beam line and BL02B2 beam line in the SPring-8. We would like to thank Prof. Dr. Tatsuo C. Kobayashi and Dr. Kenichi Kato for their experimental help at SPring-8. This work was supported by a The Exploratory Research for Advanced Technology (ERATO) research funding program “ERATO Kitagawa Integrated Pores Project” (No. 464 ) from Japan Science and Technology Agency (JST) , and also by JSPS KAKENHI Grant Number 25620187 , Grant-in-Aid for Challenging Exploratory Research. Supplementary Information for this article is available on the website of MMM. ",

year = "2014",

month = may,

day = "1",

doi = "10.1016/j.micromeso.2013.10.029",

language = "English",

volume = "189",

pages = "83--90",

journal = "Zeolites",

issn = "1387-1811",

publisher = "Elsevier",

}

TY - JOUR

T1 - Microporous structures having phenylene fin

T2 - Significance of substituent groups for rotational linkers in coordination polymers

AU - Matsuda, Ryotaro

AU - Kosaka, Wataru

AU - Kitaura, Ryo

AU - Kubota, Yoshiki

AU - Takata, Masaki

AU - Kitagawa, Susumu

N1 - Funding Information: The synchrotron radiation experiments were performed at the BL44B2 RIKEN beam line and BL02B2 beam line in the SPring-8. We would like to thank Prof. Dr. Tatsuo C. Kobayashi and Dr. Kenichi Kato for their experimental help at SPring-8. This work was supported by a The Exploratory Research for Advanced Technology (ERATO) research funding program “ERATO Kitagawa Integrated Pores Project” (No. 464 ) from Japan Science and Technology Agency (JST) , and also by JSPS KAKENHI Grant Number 25620187 , Grant-in-Aid for Challenging Exploratory Research. Supplementary Information for this article is available on the website of MMM.

PY - 2014/5/1

Y1 - 2014/5/1

N2 - Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.

AB - Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.

KW - Adsorption

KW - Metal-organic frameworks

KW - Micropore

KW - Porous coordination polymers

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UR - http://www.scopus.com/inward/citedby.url?scp=84900593702&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2013.10.029

DO - 10.1016/j.micromeso.2013.10.029

M3 - Article

AN - SCOPUS:84900593702

SN - 1387-1811

VL - 189

SP - 83

EP - 90

JO - Zeolites

JF - Zeolites

ER -

Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers

Abstract

Keywords

ASJC Scopus subject areas

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