Mild solution synthesis of plate-like and rod-like ZnO crystals

Fumihiro Gobo; Takehiro Goto; Tengfa Long; Shu Yin; Tsugio Sato

doi:10.1007/s11164-011-0244-8

Mild solution synthesis of plate-like and rod-like ZnO crystals

Fumihiro Gobo, Takehiro Goto, Tengfa Long, Shu Yin, Tsugio Sato

IMRAM - Division of Inorganic Material Research

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Micro-disks and micro-rods of ZnO were successfully synthesized by a mild solution process using zinc chloride as starting material. The morphology of the ZnO crystals changed substantially, depending on the concentrations of the Zn²⁺ ion and organic additives in the solution. A plate-like Zn ₅(OH)₈Cl₂•H₂O precursor with a layered structure could be produced in solutions with high concentrations of chloride ions. The thermal stability, including phase composition and morphology, of the as-prepared Zn₅(OH)₈Cl ₂•H₂O in air and water was investigated.

Original language	English
Pages (from-to)	211-217
Number of pages	7
Journal	Research on Chemical Intermediates
Volume	37
Issue number	2-5
DOIs	https://doi.org/10.1007/s11164-011-0244-8
Publication status	Published - 2011 Apr

Keywords

Morphological control
Simonkolleite, ZnO
Thermal stability

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10.1007/s11164-011-0244-8

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title = "Mild solution synthesis of plate-like and rod-like ZnO crystals",

abstract = "Micro-disks and micro-rods of ZnO were successfully synthesized by a mild solution process using zinc chloride as starting material. The morphology of the ZnO crystals changed substantially, depending on the concentrations of the Zn2+ ion and organic additives in the solution. A plate-like Zn 5(OH)8Cl2•H2O precursor with a layered structure could be produced in solutions with high concentrations of chloride ions. The thermal stability, including phase composition and morphology, of the as-prepared Zn5(OH)8Cl 2•H2O in air and water was investigated.",

keywords = "Morphological control, Simonkolleite, ZnO, Thermal stability",

author = "Fumihiro Gobo and Takehiro Goto and Tengfa Long and Shu Yin and Tsugio Sato",

note = "Funding Information: Acknowledgments This research was supported in part by the Management Expenses Grants for National Universities Corporations from the Ministry of Education, Culture, Sports, Science for Technology of Japan (MEXT), and by the Adaptable and Seamless Technology transfer Program through target-driven R&D, JST, and Grant-in-Aid for Science Research (No. 20360293 and No. 22651022).",

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doi = "10.1007/s11164-011-0244-8",

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T1 - Mild solution synthesis of plate-like and rod-like ZnO crystals

AU - Gobo, Fumihiro

AU - Goto, Takehiro

AU - Long, Tengfa

AU - Yin, Shu

AU - Sato, Tsugio

N1 - Funding Information: Acknowledgments This research was supported in part by the Management Expenses Grants for National Universities Corporations from the Ministry of Education, Culture, Sports, Science for Technology of Japan (MEXT), and by the Adaptable and Seamless Technology transfer Program through target-driven R&D, JST, and Grant-in-Aid for Science Research (No. 20360293 and No. 22651022).

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N2 - Micro-disks and micro-rods of ZnO were successfully synthesized by a mild solution process using zinc chloride as starting material. The morphology of the ZnO crystals changed substantially, depending on the concentrations of the Zn2+ ion and organic additives in the solution. A plate-like Zn 5(OH)8Cl2•H2O precursor with a layered structure could be produced in solutions with high concentrations of chloride ions. The thermal stability, including phase composition and morphology, of the as-prepared Zn5(OH)8Cl 2•H2O in air and water was investigated.

AB - Micro-disks and micro-rods of ZnO were successfully synthesized by a mild solution process using zinc chloride as starting material. The morphology of the ZnO crystals changed substantially, depending on the concentrations of the Zn2+ ion and organic additives in the solution. A plate-like Zn 5(OH)8Cl2•H2O precursor with a layered structure could be produced in solutions with high concentrations of chloride ions. The thermal stability, including phase composition and morphology, of the as-prepared Zn5(OH)8Cl 2•H2O in air and water was investigated.

KW - Morphological control

KW - Simonkolleite, ZnO

KW - Thermal stability

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Mild solution synthesis of plate-like and rod-like ZnO crystals

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Keywords

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