Mixed charge-ordering state of MMX-type quasi-one-dimensional iodide-bridged platinum complexes with binary countercations

Hiroaki Iguchi; Shinya Takaishi; Takashi Kajiwara; Hitoshi Miyasaka; Masahiro Yamashita; Hiroyuki Matsuzaki; Hiroshi Okamoto

doi:10.1021/ja807901p

Mixed charge-ordering state of MMX-type quasi-one-dimensional iodide-bridged platinum complexes with binary countercations

Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto

Research output: Contribution to journal › Short survey › peer-review

23 Citations (Scopus)

Abstract

A new charge-ordering (CO) state in quasi-1D iodide-bridged dinuclear Pt complexes (MMX-chains) was developed by introducing two different kinds of countercations. From crystal structure analysis, K₂(H ₃NCH₂CHMeCH₂NH₃)[Pt ₂(pop)₄I]E₄H₂O (pop = P ₂H₂O₅ ^2-) had structural features of both ACP (alternating charge-polarization) and CDW (charge-density-wave) states. Therefore, this new CO state was named ACP+CDW state. Remarkably, the structure was three dimensionally ordered, which was verified by the strong superlattice reflections observed in an X-ray oscillation photograph. Using polarized Raman and ³¹P MAS NMR spectroscopies, it was shown that there were two different Pt₂ units and four inequivalent P atoms, respectively. These results agreed with the crystal structure analysis and supported the presence of the ACP+CDW state.

Original language	English
Pages (from-to)	17668-17669
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	52
DOIs	https://doi.org/10.1021/ja807901p
Publication status	Published - 2008 Dec 31

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@article{165e3419a09e44eea1f757e1745bbd92,

title = "Mixed charge-ordering state of MMX-type quasi-one-dimensional iodide-bridged platinum complexes with binary countercations",

abstract = "A new charge-ordering (CO) state in quasi-1D iodide-bridged dinuclear Pt complexes (MMX-chains) was developed by introducing two different kinds of countercations. From crystal structure analysis, K2(H 3NCH2CHMeCH2NH3)[Pt 2(pop)4I]E4H2O (pop = P 2H2O5 2-) had structural features of both ACP (alternating charge-polarization) and CDW (charge-density-wave) states. Therefore, this new CO state was named ACP+CDW state. Remarkably, the structure was three dimensionally ordered, which was verified by the strong superlattice reflections observed in an X-ray oscillation photograph. Using polarized Raman and 31P MAS NMR spectroscopies, it was shown that there were two different Pt2 units and four inequivalent P atoms, respectively. These results agreed with the crystal structure analysis and supported the presence of the ACP+CDW state.",

author = "Hiroaki Iguchi and Shinya Takaishi and Takashi Kajiwara and Hitoshi Miyasaka and Masahiro Yamashita and Hiroyuki Matsuzaki and Hiroshi Okamoto",

year = "2008",

month = dec,

day = "31",

doi = "10.1021/ja807901p",

language = "English",

volume = "130",

pages = "17668--17669",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Mixed charge-ordering state of MMX-type quasi-one-dimensional iodide-bridged platinum complexes with binary countercations

AU - Iguchi, Hiroaki

AU - Takaishi, Shinya

AU - Kajiwara, Takashi

AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

AU - Matsuzaki, Hiroyuki

AU - Okamoto, Hiroshi

PY - 2008/12/31

Y1 - 2008/12/31

N2 - A new charge-ordering (CO) state in quasi-1D iodide-bridged dinuclear Pt complexes (MMX-chains) was developed by introducing two different kinds of countercations. From crystal structure analysis, K2(H 3NCH2CHMeCH2NH3)[Pt 2(pop)4I]E4H2O (pop = P 2H2O5 2-) had structural features of both ACP (alternating charge-polarization) and CDW (charge-density-wave) states. Therefore, this new CO state was named ACP+CDW state. Remarkably, the structure was three dimensionally ordered, which was verified by the strong superlattice reflections observed in an X-ray oscillation photograph. Using polarized Raman and 31P MAS NMR spectroscopies, it was shown that there were two different Pt2 units and four inequivalent P atoms, respectively. These results agreed with the crystal structure analysis and supported the presence of the ACP+CDW state.

AB - A new charge-ordering (CO) state in quasi-1D iodide-bridged dinuclear Pt complexes (MMX-chains) was developed by introducing two different kinds of countercations. From crystal structure analysis, K2(H 3NCH2CHMeCH2NH3)[Pt 2(pop)4I]E4H2O (pop = P 2H2O5 2-) had structural features of both ACP (alternating charge-polarization) and CDW (charge-density-wave) states. Therefore, this new CO state was named ACP+CDW state. Remarkably, the structure was three dimensionally ordered, which was verified by the strong superlattice reflections observed in an X-ray oscillation photograph. Using polarized Raman and 31P MAS NMR spectroscopies, it was shown that there were two different Pt2 units and four inequivalent P atoms, respectively. These results agreed with the crystal structure analysis and supported the presence of the ACP+CDW state.

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U2 - 10.1021/ja807901p

DO - 10.1021/ja807901p

M3 - Short survey

AN - SCOPUS:67749127572

SN - 0002-7863

VL - 130

SP - 17668

EP - 17669

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 52

ER -

Mixed charge-ordering state of MMX-type quasi-one-dimensional iodide-bridged platinum complexes with binary countercations

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