MnIII salen-type single-molecule magnet fixed in a two-dimensional network

Chihiro Kachi-Terajima; Elina Mori; Tasuku Eiba; Toshiaki Saito; Chikahide Kanadani; Takafumi Kitazawa; Hitoshi Miyasaka

doi:10.1246/cl.2010.94

Mn^III salen-type single-molecule magnet fixed in a two-dimensional network

Chihiro Kachi-Terajima, Elina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa, Hitoshi Miyasaka

IMR - Materials Development Division

Toho University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)₆}](ClO₄)·9H₂0 (2) (saltmen^2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn₂(saltmen)₂]²⁺ subunit as a single-molecule magnet with an S_T = 4 spin ground state, indicating that the Mn^III dimer is magnetically isolated not only by the diamagnetic [Co(CN)₆]^3- unit but also by the space between the layers.

Original language	English
Pages (from-to)	94-95
Number of pages	2
Journal	Chemistry Letters
Volume	39
Issue number	2
DOIs	https://doi.org/10.1246/cl.2010.94
Publication status	Published - 2010

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title = "MnIII salen-type single-molecule magnet fixed in a two-dimensional network",

abstract = "A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H20 (2) (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3- unit but also by the space between the layers.",

author = "Chihiro Kachi-Terajima and Elina Mori and Tasuku Eiba and Toshiaki Saito and Chikahide Kanadani and Takafumi Kitazawa and Hitoshi Miyasaka",

year = "2010",

doi = "10.1246/cl.2010.94",

language = "English",

volume = "39",

pages = "94--95",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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TY - JOUR

T1 - MnIII salen-type single-molecule magnet fixed in a two-dimensional network

AU - Kachi-Terajima, Chihiro

AU - Mori, Elina

AU - Eiba, Tasuku

AU - Saito, Toshiaki

AU - Kanadani, Chikahide

AU - Kitazawa, Takafumi

AU - Miyasaka, Hitoshi

PY - 2010

Y1 - 2010

N2 - A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H20 (2) (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3- unit but also by the space between the layers.

AB - A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H20 (2) (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3- unit but also by the space between the layers.

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VL - 39

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EP - 95

JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

ER -

Mn^III salen-type single-molecule magnet fixed in a two-dimensional network

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