Morphology control of polymer blends by a chemical pinning of spinodal decomposition

Takeji Hashimoto, Mikihito Takenaka, Hiroshi Jinnai

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)


The ordering dynamics of polymer blends were investigated at the early-to-late stage of spinodal decomposition. The blends studied were 50/50 wt/wt mixtures of polyisoprene and styrene-butadiene random copolymer containing 15 wt% styrene which undergo a very slow ordering process via spinodal decomposition. We succeeded in chemical pinning of a slowly growing phase-separated domain-structure by crosslinking the polymers with a peroxide at various stages of spinodal decomposition. The chemical pinning locks-in the phase-separating domain structures of a certain spatial scale and amplitude of the concentration fluctuations.

Original languageEnglish
Pages (from-to)177-179
Number of pages3
JournalPolymer communications Guildford
Issue number6
Publication statusPublished - 1989 Jun 1
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)


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