TY - JOUR
T1 - M+(crown ether) supramolecular cations (M+ = K+, Rb+, NH4+) for controlling magnetic properties of monovalent [Ni(dmit)2]- salts
AU - Takamatsu, Nobuhiro
AU - Akutagawa, Tomoyuki
AU - Hasegawa, Tatsuo
AU - Nakamura, Takayoshi
AU - Inabe, Tamotsu
AU - Fujita, Wataru
AU - Awaga, Kunio
PY - 2000
Y1 - 2000
N2 - Supramolecular cations (SC+) of K+, Rb+, or NH4+(crown ether) were incorporated into the monovalent [Ni(dmit)2]- salts. The K+ and Rb+(DA18-crown-6) units had a planar disk-shaped SC+ structure, while the [NH4+(150-crown-5)2]2 was the barrel type SC+ structure. The [Ni(dmit)2]-arrangement and magnetic properties of these salts depended on the coordination properties in the cation structures.
AB - Supramolecular cations (SC+) of K+, Rb+, or NH4+(crown ether) were incorporated into the monovalent [Ni(dmit)2]- salts. The K+ and Rb+(DA18-crown-6) units had a planar disk-shaped SC+ structure, while the [NH4+(150-crown-5)2]2 was the barrel type SC+ structure. The [Ni(dmit)2]-arrangement and magnetic properties of these salts depended on the coordination properties in the cation structures.
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U2 - 10.1080/10587250008023520
DO - 10.1080/10587250008023520
M3 - Conference article
AN - SCOPUS:0033658679
SN - 1058-725X
VL - 343
SP - 163
EP - 168
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
T2 - Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metals Complexes (AMC'99)
Y2 - 30 November 1999 through 2 December 1999
ER -