Multifunctionalities of single-molecule magnets with electrical conductivities

Kazuya Kubo; Hiroki Hiraga; Hitoshi Miyasaka; Masahiro Yamashita

doi:10.4032/9789814364300

Multifunctionalities of single-molecule magnets with electrical conductivities

Kazuya Kubo, Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita

Research output: Chapter in Book/Report/Conference proceeding › Chapter

1 Citation (Scopus)

Abstract

A new strategy for the preparation of hybridized materials with coexisting magnetism and conductivity was developed using single-molecule magnets (SMMs) and molecular conductors. The new strategy has various advantages including easy modification of their molecular and electronic features. The hybridized materials, [{Mn^II₂ Mn^III₂(hmp)₆(MeCN)₂}{Pt(mnt) ₂}_x][Pt(mnt)₂]₂·nMeCN (x = 2 or 4, n = 0, or 2) and [Mn₂(5-MeOsaltmen)₂(solvent)_x][Ni(dmit) ₂]_y·n solvent (x = 0 or 2, y = 2, or 7, n = 0 or 4, solvent = acetone or MeCN), were prepared from cationic SMMs and acceptor types of molecular conductors by diffusion or electrochemical crystallization methods. In this review, the strategy for preparation of hybrid materials based on SMMs and molecular conductors and physical properties of the salts are discussed.

Original language	English
Title of host publication	Multifunctional Molecular Materials
Publisher	Pan Stanford Publishing Pte. Ltd.
Pages	61-103
Number of pages	43
ISBN (Print)	9789814364294
DOIs	https://doi.org/10.4032/9789814364300
Publication status	Published - 2012 Dec 31
Externally published	Yes

ASJC Scopus subject areas

Medicine(all)
Materials Science(all)

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10.4032/9789814364300

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abstract = "A new strategy for the preparation of hybridized materials with coexisting magnetism and conductivity was developed using single-molecule magnets (SMMs) and molecular conductors. The new strategy has various advantages including easy modification of their molecular and electronic features. The hybridized materials, [{MnII2 MnIII2(hmp)6(MeCN)2}{Pt(mnt) 2}x][Pt(mnt)2]2·nMeCN (x = 2 or 4, n = 0, or 2) and [Mn2(5-MeOsaltmen)2(solvent)x][Ni(dmit) 2]y·n solvent (x = 0 or 2, y = 2, or 7, n = 0 or 4, solvent = acetone or MeCN), were prepared from cationic SMMs and acceptor types of molecular conductors by diffusion or electrochemical crystallization methods. In this review, the strategy for preparation of hybrid materials based on SMMs and molecular conductors and physical properties of the salts are discussed.",

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AU - Kubo, Kazuya

AU - Hiraga, Hiroki

AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

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Y1 - 2012/12/31

N2 - A new strategy for the preparation of hybridized materials with coexisting magnetism and conductivity was developed using single-molecule magnets (SMMs) and molecular conductors. The new strategy has various advantages including easy modification of their molecular and electronic features. The hybridized materials, [{MnII2 MnIII2(hmp)6(MeCN)2}{Pt(mnt) 2}x][Pt(mnt)2]2·nMeCN (x = 2 or 4, n = 0, or 2) and [Mn2(5-MeOsaltmen)2(solvent)x][Ni(dmit) 2]y·n solvent (x = 0 or 2, y = 2, or 7, n = 0 or 4, solvent = acetone or MeCN), were prepared from cationic SMMs and acceptor types of molecular conductors by diffusion or electrochemical crystallization methods. In this review, the strategy for preparation of hybrid materials based on SMMs and molecular conductors and physical properties of the salts are discussed.

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ER -

Multifunctionalities of single-molecule magnets with electrical conductivities

Abstract

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