NaH-mediated direct C-H arylation in the presence of 1,10-phenanthroline

Kanako Nozawa-Kumada, Yuki Iwakawa, So Onuma, Masanori Shigeno, Yoshinori Kondo

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)


Transition-metal-free coupling of haloarenes with unactivated arenes has been developed in the presence of NaH and 1,10-phenanthroline. Various haloarenes bearing methyl, methoxy, halogen (fluoride, chloride, and bromide), cyano, trifluoromethyl, ester, and amide groups can be cross-coupled with unactivated arenes, or heteroarenes in this reaction.

Original languageEnglish
Pages (from-to)7773-7776
Number of pages4
JournalChemical Communications
Issue number56
Publication statusPublished - 2020 Jul 18


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