Nanometer-sized shell molecules that confine endohedral polymerizing units

Takashi Murase; Sota Sato; Makoto Fujita

doi:10.1002/anie.200603561

Nanometer-sized shell molecules that confine endohedral polymerizing units

Takashi Murase, Sota Sato, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Polymerization in a nutshell: A discrete spherical Pd₁₂L ₂₄ complex was prepared that confines 24 tethered methyl methacrylate (MMA) units internally (see picture; shell blue, Pd yellow, O red, C gray; MMA shown as space-filling representation). Endohedral radical polymerization of the monomer proceeds efficiently as a result of the high concentration of MMA units within the restricted space of the core (inner diameter: 3.7 nm). (Figure Presented).

Original language	English
Pages (from-to)	1083-1085
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	7
DOIs	https://doi.org/10.1002/anie.200603561
Publication status	Published - 2007
Externally published	Yes

Keywords

Cage compounds
Nanostructures
Palladium
Polymerization
Self-assembly

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200603561

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abstract = "Polymerization in a nutshell: A discrete spherical Pd12L 24 complex was prepared that confines 24 tethered methyl methacrylate (MMA) units internally (see picture; shell blue, Pd yellow, O red, C gray; MMA shown as space-filling representation). Endohedral radical polymerization of the monomer proceeds efficiently as a result of the high concentration of MMA units within the restricted space of the core (inner diameter: 3.7 nm). (Figure Presented).",

keywords = "Cage compounds, Nanostructures, Palladium, Polymerization, Self-assembly",

author = "Takashi Murase and Sota Sato and Makoto Fujita",

year = "2007",

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language = "English",

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AU - Murase, Takashi

AU - Sato, Sota

AU - Fujita, Makoto

PY - 2007

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N2 - Polymerization in a nutshell: A discrete spherical Pd12L 24 complex was prepared that confines 24 tethered methyl methacrylate (MMA) units internally (see picture; shell blue, Pd yellow, O red, C gray; MMA shown as space-filling representation). Endohedral radical polymerization of the monomer proceeds efficiently as a result of the high concentration of MMA units within the restricted space of the core (inner diameter: 3.7 nm). (Figure Presented).

AB - Polymerization in a nutshell: A discrete spherical Pd12L 24 complex was prepared that confines 24 tethered methyl methacrylate (MMA) units internally (see picture; shell blue, Pd yellow, O red, C gray; MMA shown as space-filling representation). Endohedral radical polymerization of the monomer proceeds efficiently as a result of the high concentration of MMA units within the restricted space of the core (inner diameter: 3.7 nm). (Figure Presented).

KW - Cage compounds

KW - Nanostructures

KW - Palladium

KW - Polymerization

KW - Self-assembly

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JF - Angewandte Chemie - International Edition

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ER -

Nanometer-sized shell molecules that confine endohedral polymerizing units

Abstract

Keywords

ASJC Scopus subject areas

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