Naphtho-and anthra-disilacyclobutadienes

Shintaro Ishida, Shohei Sugawara, Shunya Honda, Takeaki Iwamoto

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Naphthodislacyclobutadiene 3 and anthradisilacyclobutadiene 4 were synthesized and characterized. In these compounds, the diatropic ring current on the benzene ring adjacent to the disilacyclobutadiene moiety decreases while that on the other benzene rings remains intact. The longest-wavelength absorption bands of 3 and 4 were hypsochromically shifted compared to those of benzodisilacyclobutadiene 1a despite the extended π-electron systems.

Original languageEnglish
Pages (from-to)15072-15075
Number of pages4
JournalChemical Communications
Volume56
Issue number95
DOIs
Publication statusPublished - 2020 Dec 11

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