Nascent internal state distributions of ZnH(X2Σ +) produced in the reactions of Zn(41P1) with some alkane hydrocarbons

Hironobu Umemoto; Shigeru Tsunashima; Hiroyuki Ikeda; Kazuto Takano; Kazuya Kuwahara; Kei Sato; Keiichi Yokoyama; Fuminori Misaizu; Kiyokazu Fuke

doi:10.1063/1.467402

Nascent internal state distributions of ZnH(X²Σ ⁺) produced in the reactions of Zn(4¹P₁) with some alkane hydrocarbons

Hironobu Umemoto, Shigeru Tsunashima, Hiroyuki Ikeda, Kazuto Takano, Kazuya Kuwahara, Kei Sato, Keiichi Yokoyama, Fuminori Misaizu, Kiyokazu Fuke

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The reactions of Zn(4 ¹P₁) with CH₄, C₂H₆, C₃H₈, and C(CH ₃)₄ were studied by employing a laser pump-and-probe technique. The nascent rotational and vibrational state distributions of ZnH(X ²Σ⁺) were determined. These distributions were compared with those predicted by statistical models. The distributions for C(CH₃)₄ resembled to the statistical ones, while those for simple alkanes such as CH₄ were a little hotter than the statistical ones. These results suggest that the reaction proceeds via a relatively long-lived insertive complex. There was no great difference in the production yields of ZnH, although that for CH₄ was the largest.

Original language	English
Pages (from-to)	4803-4808
Number of pages	6
Journal	The Journal of Chemical Physics
Volume	101
Issue number	6
DOIs	https://doi.org/10.1063/1.467402
Publication status	Published - 1994 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Nascent internal state distributions of ZnH(X2Σ +) produced in the reactions of Zn(41P1) with some alkane hydrocarbons",

abstract = "The reactions of Zn(4 1P1) with CH4, C2H6, C3H8, and C(CH 3)4 were studied by employing a laser pump-and-probe technique. The nascent rotational and vibrational state distributions of ZnH(X 2Σ+) were determined. These distributions were compared with those predicted by statistical models. The distributions for C(CH3)4 resembled to the statistical ones, while those for simple alkanes such as CH4 were a little hotter than the statistical ones. These results suggest that the reaction proceeds via a relatively long-lived insertive complex. There was no great difference in the production yields of ZnH, although that for CH4 was the largest.",

author = "Hironobu Umemoto and Shigeru Tsunashima and Hiroyuki Ikeda and Kazuto Takano and Kazuya Kuwahara and Kei Sato and Keiichi Yokoyama and Fuminori Misaizu and Kiyokazu Fuke",

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T1 - Nascent internal state distributions of ZnH(X2Σ +) produced in the reactions of Zn(41P1) with some alkane hydrocarbons

AU - Umemoto, Hironobu

AU - Tsunashima, Shigeru

AU - Ikeda, Hiroyuki

AU - Takano, Kazuto

AU - Kuwahara, Kazuya

AU - Sato, Kei

AU - Yokoyama, Keiichi

AU - Misaizu, Fuminori

AU - Fuke, Kiyokazu

PY - 1994/1/1

Y1 - 1994/1/1

N2 - The reactions of Zn(4 1P1) with CH4, C2H6, C3H8, and C(CH 3)4 were studied by employing a laser pump-and-probe technique. The nascent rotational and vibrational state distributions of ZnH(X 2Σ+) were determined. These distributions were compared with those predicted by statistical models. The distributions for C(CH3)4 resembled to the statistical ones, while those for simple alkanes such as CH4 were a little hotter than the statistical ones. These results suggest that the reaction proceeds via a relatively long-lived insertive complex. There was no great difference in the production yields of ZnH, although that for CH4 was the largest.

AB - The reactions of Zn(4 1P1) with CH4, C2H6, C3H8, and C(CH 3)4 were studied by employing a laser pump-and-probe technique. The nascent rotational and vibrational state distributions of ZnH(X 2Σ+) were determined. These distributions were compared with those predicted by statistical models. The distributions for C(CH3)4 resembled to the statistical ones, while those for simple alkanes such as CH4 were a little hotter than the statistical ones. These results suggest that the reaction proceeds via a relatively long-lived insertive complex. There was no great difference in the production yields of ZnH, although that for CH4 was the largest.

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Nascent internal state distributions of ZnH(X²Σ ⁺) produced in the reactions of Zn(4¹P₁) with some alkane hydrocarbons

Abstract

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