NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

Weili Si; Shirong Lu; Naoki Asao; Ming Bao; Yoshinori Yamamoto; Tienan Jin

doi:10.1039/c4cc07780f

NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

Weili Si, Shirong Lu, Naoki Asao, Ming Bao, Yoshinori Yamamoto, Tienan Jin

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles.

Original language	English
Pages (from-to)	15730-15732
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	99
DOIs	https://doi.org/10.1039/c4cc07780f
Publication status	Published - 2014 Nov 18

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abstract = "We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles.",

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AU - Si, Weili

AU - Lu, Shirong

AU - Asao, Naoki

AU - Bao, Ming

AU - Yamamoto, Yoshinori

AU - Jin, Tienan

PY - 2014/11/18

Y1 - 2014/11/18

N2 - We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles.

AB - We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles.

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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

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