New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4] · CH3CN

Masamichi Umemiya; Makoto Goto; Norihito Kobayashi; Shinya Takaishi; Takashi Kajiwara; Masahiro Yamashita; Hitoshi Miyasaka; Ken Ichi Sugiura; Harutaka Watanabe; Daichi Suzuki; Hiroshi Ito; Shin Ichi Kuroda

doi:10.1246/cl.2006.368

New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)₃[Cr(isoq)₂(NCS)₄] and (DMET)₃[Cr(phen)(NCS)₄] · CH₃CN

Masamichi Umemiya, Makoto Goto, Norihito Kobayashi, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita, Hitoshi Miyasaka, Ken Ichi Sugiura, Harutaka Watanabe, Daichi Suzuki, Hiroshi Ito, Shin Ichi Kuroda

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4 Citations (Scopus)

Abstract

Two charge-transfer salts (DMET)₃[Cr(isoq)₂(NCS) ₄] (1) and (DMET)₃[Cr(phen)(NCS)₄] · CH₃CN (2) have been prepared and characterized. The single-crystal X-ray crystallography revealed that the structures of both salts consist of segregated columns of DMET and metal complex anions. The magnetic and transport properties have shown that these salts are paramagnetic semiconductors.

Original language	English
Pages (from-to)	368-369
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	4
DOIs	https://doi.org/10.1246/cl.2006.368
Publication status	Published - 2006 Apr 5

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Umemiya, M., Goto, M., Kobayashi, N., Takaishi, S., Kajiwara, T., Yamashita, M., Miyasaka, H., Sugiura, K. I., Watanabe, H., Suzuki, D., Ito, H., & Kuroda, S. I. (2006). New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)₃[Cr(isoq)₂(NCS)₄] and (DMET)₃[Cr(phen)(NCS)₄] · CH₃CN. Chemistry Letters, 35(4), 368-369. https://doi.org/10.1246/cl.2006.368

@article{09bb3b603b6e4453a98f94a23e9fe53b,

title = "New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4] · CH3CN",

abstract = "Two charge-transfer salts (DMET)3[Cr(isoq)2(NCS) 4] (1) and (DMET)3[Cr(phen)(NCS)4] · CH3CN (2) have been prepared and characterized. The single-crystal X-ray crystallography revealed that the structures of both salts consist of segregated columns of DMET and metal complex anions. The magnetic and transport properties have shown that these salts are paramagnetic semiconductors.",

author = "Masamichi Umemiya and Makoto Goto and Norihito Kobayashi and Shinya Takaishi and Takashi Kajiwara and Masahiro Yamashita and Hitoshi Miyasaka and Sugiura, {Ken Ichi} and Harutaka Watanabe and Daichi Suzuki and Hiroshi Ito and Kuroda, {Shin Ichi}",

year = "2006",

month = apr,

day = "5",

doi = "10.1246/cl.2006.368",

language = "English",

volume = "35",

pages = "368--369",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "4",

}

Umemiya, M, Goto, M, Kobayashi, N, Takaishi, S, Kajiwara, T, Yamashita, M, Miyasaka, H, Sugiura, KI, Watanabe, H, Suzuki, D, Ito, H & Kuroda, SI 2006, 'New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)₃[Cr(isoq)₂(NCS)₄] and (DMET)₃[Cr(phen)(NCS)₄] · CH₃CN', Chemistry Letters, vol. 35, no. 4, pp. 368-369. https://doi.org/10.1246/cl.2006.368

TY - JOUR

T1 - New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions

T2 - (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4] · CH3CN

AU - Umemiya, Masamichi

AU - Goto, Makoto

AU - Kobayashi, Norihito

AU - Takaishi, Shinya

AU - Kajiwara, Takashi

AU - Yamashita, Masahiro

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken Ichi

AU - Watanabe, Harutaka

AU - Suzuki, Daichi

AU - Ito, Hiroshi

AU - Kuroda, Shin Ichi

PY - 2006/4/5

Y1 - 2006/4/5

N2 - Two charge-transfer salts (DMET)3[Cr(isoq)2(NCS) 4] (1) and (DMET)3[Cr(phen)(NCS)4] · CH3CN (2) have been prepared and characterized. The single-crystal X-ray crystallography revealed that the structures of both salts consist of segregated columns of DMET and metal complex anions. The magnetic and transport properties have shown that these salts are paramagnetic semiconductors.

AB - Two charge-transfer salts (DMET)3[Cr(isoq)2(NCS) 4] (1) and (DMET)3[Cr(phen)(NCS)4] · CH3CN (2) have been prepared and characterized. The single-crystal X-ray crystallography revealed that the structures of both salts consist of segregated columns of DMET and metal complex anions. The magnetic and transport properties have shown that these salts are paramagnetic semiconductors.

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DO - 10.1246/cl.2006.368

M3 - Article

AN - SCOPUS:33745814725

SN - 0366-7022

VL - 35

SP - 368

EP - 369

JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)₃[Cr(isoq)₂(NCS)₄] and (DMET)₃[Cr(phen)(NCS)₄] · CH₃CN

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