TY - JOUR
T1 - New stable metallic salt based on a donor molecule containing peri-ditellurium bridges, TMTTeN(SCN)0.88
AU - Ojima, Emiko
AU - Narymbetov, Bakhyt Zh
AU - Fujiwara, Hideki
AU - Kobayashi, Hayao
AU - Kobayashi, Akiko
AU - Takimiya, Kazuo
AU - Otsubo, Tetsuo
AU - Ogura, Fumio
PY - 1999
Y1 - 1999
N2 - A new stable organic metal, TMTTeN(SCN)0.88, where TMTTeN is 2,3,6,7-tetramethylnaphtho[1,8-cd:4,5-c′d′]bis[1,2] ditellurole, was obtained. The donors are stacked to form columns and three-dimensional network is developed through Te⋯Te contacts. The salt is highly conductive and keeps metallic behavior down to 4.2 K. Furthermore the salt exhibits Pauli paramagnetic behavior down to 2 K. The extended Hückel tight-binding band calculation was examined.
AB - A new stable organic metal, TMTTeN(SCN)0.88, where TMTTeN is 2,3,6,7-tetramethylnaphtho[1,8-cd:4,5-c′d′]bis[1,2] ditellurole, was obtained. The donors are stacked to form columns and three-dimensional network is developed through Te⋯Te contacts. The salt is highly conductive and keeps metallic behavior down to 4.2 K. Furthermore the salt exhibits Pauli paramagnetic behavior down to 2 K. The extended Hückel tight-binding band calculation was examined.
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U2 - 10.1246/cl.1999.845
DO - 10.1246/cl.1999.845
M3 - Article
AN - SCOPUS:0033245601
SN - 0366-7022
SP - 845
EP - 846
JO - Chemistry Letters
JF - Chemistry Letters
IS - 8
ER -