New synthetic route to the highly strained cores of C-1027 and neocarzinostatin chromophores

I. Sato; K. Toyama; T. Kikuchi; M. Hirama

doi:10.1055/s-1998-1983

New synthetic route to the highly strained cores of C-1027 and neocarzinostatin chromophores

I. Sato, K. Toyama, T. Kikuchi, M. Hirama

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Efficient construction of the bicyclo[7.3.0]dodecenediyne cores of chromophore of C-1027 (1) and neocarzinostatin (2) was obtained via the C-C bond formation at C5-C6 using the LiN(SiMe₃)₂/ CeCl₃-mediated acetylide-aldehyde condensation reaction.

Original language	English
Pages (from-to)	1308-1310
Number of pages	3
Journal	Synlett
Issue number	12
DOIs	https://doi.org/10.1055/s-1998-1983
Publication status	Published - 1998 Dec

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1998-1983

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title = "New synthetic route to the highly strained cores of C-1027 and neocarzinostatin chromophores",

abstract = "Efficient construction of the bicyclo[7.3.0]dodecenediyne cores of chromophore of C-1027 (1) and neocarzinostatin (2) was obtained via the C-C bond formation at C5-C6 using the LiN(SiMe3)2/ CeCl3-mediated acetylide-aldehyde condensation reaction.",

author = "I. Sato and K. Toyama and T. Kikuchi and M. Hirama",

year = "1998",

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doi = "10.1055/s-1998-1983",

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T1 - New synthetic route to the highly strained cores of C-1027 and neocarzinostatin chromophores

AU - Sato, I.

AU - Toyama, K.

AU - Kikuchi, T.

AU - Hirama, M.

PY - 1998/12

Y1 - 1998/12

N2 - Efficient construction of the bicyclo[7.3.0]dodecenediyne cores of chromophore of C-1027 (1) and neocarzinostatin (2) was obtained via the C-C bond formation at C5-C6 using the LiN(SiMe3)2/ CeCl3-mediated acetylide-aldehyde condensation reaction.

AB - Efficient construction of the bicyclo[7.3.0]dodecenediyne cores of chromophore of C-1027 (1) and neocarzinostatin (2) was obtained via the C-C bond formation at C5-C6 using the LiN(SiMe3)2/ CeCl3-mediated acetylide-aldehyde condensation reaction.

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DO - 10.1055/s-1998-1983

M3 - Article

AN - SCOPUS:0003111457

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IS - 12

ER -

New synthetic route to the highly strained cores of C-1027 and neocarzinostatin chromophores

Abstract

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