NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers

Ilya D. Gridnev; Fabio Pichierri

doi:10.1039/b311885a

NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers

Ilya D. Gridnev, Fabio Pichierri

ENG - Chemical Engineering

Tohoku University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Reaction of [2.2]paracyclophane with K/Na alloy in THF gives a p-xylylenyl dianion together with its dimer and trimer which are relatively stable at low temperatures; at ambient temperatures further polymerization takes place.

Original language	English
Pages (from-to)	150-151
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	2
DOIs	https://doi.org/10.1039/b311885a
Publication status	Published - 2004

Access to Document

10.1039/b311885a

Cite this

@article{edebaab483a744dbb34b9e7957aac49d,

title = "NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers",

abstract = "Reaction of [2.2]paracyclophane with K/Na alloy in THF gives a p-xylylenyl dianion together with its dimer and trimer which are relatively stable at low temperatures; at ambient temperatures further polymerization takes place.",

author = "Gridnev, {Ilya D.} and Fabio Pichierri",

year = "2004",

doi = "10.1039/b311885a",

language = "English",

volume = "4",

pages = "150--151",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - NMR and computational studies of the chemical reduction of [2.2]paracyclophane

T2 - formation of dianionic p-xylenyl oligomers

AU - Gridnev, Ilya D.

AU - Pichierri, Fabio

PY - 2004

Y1 - 2004

N2 - Reaction of [2.2]paracyclophane with K/Na alloy in THF gives a p-xylylenyl dianion together with its dimer and trimer which are relatively stable at low temperatures; at ambient temperatures further polymerization takes place.

AB - Reaction of [2.2]paracyclophane with K/Na alloy in THF gives a p-xylylenyl dianion together with its dimer and trimer which are relatively stable at low temperatures; at ambient temperatures further polymerization takes place.

UR - http://www.scopus.com/inward/record.url?scp=1642439243&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1642439243&partnerID=8YFLogxK

U2 - 10.1039/b311885a

DO - 10.1039/b311885a

M3 - Article

AN - SCOPUS:1642439243

SN - 1359-7345

VL - 4

SP - 150

EP - 151

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers

Abstract

Access to Document

Other files and links

Fingerprint

Cite this