Noble gases in angrites Northwest Africa 1296, 2999/4931, 4590, and 4801: Evolution history inferred from noble gas signatures

Noble gases in the five angrites Northwest Africa (NWA) 1296, 2999, 4590, 4801, and 4931 were analyzed with total melting and stepwise heating methods. The noble gases consist of in situ components: spallogenic, radiogenic, nucleogenic, and fission. Cosmic-ray exposure ages of the angrites (including literature data) spread uniformly from <0.2 to 56 Ma, and coarse-grained angrites have longer exposure ages than fine-grained angrites. It is implied that the parent bodies from which the two subgroups of angrites were ejected are different and have distinct orbital elements. The ²⁴⁴Pu-¹³⁶Xe relative ages of the angrites obtained by using ²⁴⁴Pu/¹⁵⁰Nd ratios are as old as that of Angra dos Reis, reflecting their early formation. On the other hand, another method to obtain ²⁴⁴Pu-¹³⁶Xe relative ages, using fission ¹³⁶Xe, spallogenic ¹²⁶Xe, and Ba/REE ratios, yields systematically older ²⁴⁴Pu-¹³⁶Xe ages than those obtained by using ²⁴⁴Pu/¹⁵⁰Nd ratios, which is explained by apparently high Ba/REE ratios caused by Ba contamination during terrestrial weathering. The ²⁴⁴Pu/²³⁸U ratio at 4.56 Ga of angrites is estimated as 0.0061 ± 0.0028, which is consistent with those for chondrules, chondrites, achondrites, and a terrestrial zircon. It is suggested that initial ²⁴⁴Pu/²³⁸U ratio has been spatially homogeneous at least in the inner part of the early solar system.