Non-classically controlled sign in a 1.6 tesla magnetic circularly polarized luminescence of three pyrenes in a chloroform and a PMMA film

Daiki Kaji; Hana Okada; Nobuyuki Hara; Yoshiro Kondo; Satoko Suzuki; Makoto Miyasaka; Michiya Fujiki; Yoshitane Imai

doi:10.1246/cl.200136

Non-classically controlled sign in a 1.6 tesla magnetic circularly polarized luminescence of three pyrenes in a chloroform and a PMMA film

Daiki Kaji, Hana Okada, Nobuyuki Hara, Yoshiro Kondo, Satoko Suzuki, Makoto Miyasaka, Michiya Fujiki, Yoshitane Imai

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Molecular pyrene, 1-hydroxylpyrene, and 2-hydroxypyrene in chloroform and embedded in poly(methyl methacrylate) film reveal mirror-image magnetic circularly polarized luminescence (MCPL) when south (S)-up or north (N)-up direction of the longitudinal external magnetic field of 1.6 T to unpolarized incident light (Faraday geometry) is employed. The «g_MCPL« magnitude is on the order of 10¹³ T¹¹ in 374416 nm. The sign of MCPL is controlled by the S-up and N-up geometry and by the position (1- or 2-) of the hydroxy group.

Original language	English
Pages (from-to)	674-676
Number of pages	3
Journal	Chemistry Letters
Volume	49
Issue number	6
DOIs	https://doi.org/10.1246/cl.200136
Publication status	Published - 2020 Jun
Externally published	Yes

Keywords

Fluorescence
Magnetic circularly polarized luminescence
Pyrene

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.200136

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@article{a3b211a8267948e7ab2987d505954ca0,

title = "Non-classically controlled sign in a 1.6 tesla magnetic circularly polarized luminescence of three pyrenes in a chloroform and a PMMA film",

abstract = "Molecular pyrene, 1-hydroxylpyrene, and 2-hydroxypyrene in chloroform and embedded in poly(methyl methacrylate) film reveal mirror-image magnetic circularly polarized luminescence (MCPL) when south (S)-up or north (N)-up direction of the longitudinal external magnetic field of 1.6 T to unpolarized incident light (Faraday geometry) is employed. The «gMCPL« magnitude is on the order of 1013 T11 in 374416 nm. The sign of MCPL is controlled by the S-up and N-up geometry and by the position (1- or 2-) of the hydroxy group.",

keywords = "Fluorescence, Magnetic circularly polarized luminescence, Pyrene",

author = "Daiki Kaji and Hana Okada and Nobuyuki Hara and Yoshiro Kondo and Satoko Suzuki and Makoto Miyasaka and Michiya Fujiki and Yoshitane Imai",

note = "Funding Information: This study was supported by Grant-in-Aid for Scientific Research (nos. 18K05094 and 19H04600) from the Ministry of Education, Culture, Sports, Science and Technology/Japan Society for the Promotion of Science and the Research Foundation for the Electrotechnology of Chubu, KDDI, and Futaba. Publisher Copyright: {\textcopyright} 2020 The Chemical Society of Japan",

year = "2020",

month = jun,

doi = "10.1246/cl.200136",

language = "English",

volume = "49",

pages = "674--676",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "6",

}

TY - JOUR

T1 - Non-classically controlled sign in a 1.6 tesla magnetic circularly polarized luminescence of three pyrenes in a chloroform and a PMMA film

AU - Kaji, Daiki

AU - Okada, Hana

AU - Hara, Nobuyuki

AU - Kondo, Yoshiro

AU - Suzuki, Satoko

AU - Miyasaka, Makoto

AU - Fujiki, Michiya

AU - Imai, Yoshitane

N1 - Funding Information: This study was supported by Grant-in-Aid for Scientific Research (nos. 18K05094 and 19H04600) from the Ministry of Education, Culture, Sports, Science and Technology/Japan Society for the Promotion of Science and the Research Foundation for the Electrotechnology of Chubu, KDDI, and Futaba. Publisher Copyright: © 2020 The Chemical Society of Japan

PY - 2020/6

Y1 - 2020/6

N2 - Molecular pyrene, 1-hydroxylpyrene, and 2-hydroxypyrene in chloroform and embedded in poly(methyl methacrylate) film reveal mirror-image magnetic circularly polarized luminescence (MCPL) when south (S)-up or north (N)-up direction of the longitudinal external magnetic field of 1.6 T to unpolarized incident light (Faraday geometry) is employed. The «gMCPL« magnitude is on the order of 1013 T11 in 374416 nm. The sign of MCPL is controlled by the S-up and N-up geometry and by the position (1- or 2-) of the hydroxy group.

AB - Molecular pyrene, 1-hydroxylpyrene, and 2-hydroxypyrene in chloroform and embedded in poly(methyl methacrylate) film reveal mirror-image magnetic circularly polarized luminescence (MCPL) when south (S)-up or north (N)-up direction of the longitudinal external magnetic field of 1.6 T to unpolarized incident light (Faraday geometry) is employed. The «gMCPL« magnitude is on the order of 1013 T11 in 374416 nm. The sign of MCPL is controlled by the S-up and N-up geometry and by the position (1- or 2-) of the hydroxy group.

KW - Fluorescence

KW - Magnetic circularly polarized luminescence

KW - Pyrene

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U2 - 10.1246/cl.200136

DO - 10.1246/cl.200136

M3 - Article

AN - SCOPUS:85087046401

SN - 0366-7022

VL - 49

SP - 674

EP - 676

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Non-classically controlled sign in a 1.6 tesla magnetic circularly polarized luminescence of three pyrenes in a chloroform and a PMMA film

Abstract

Keywords

ASJC Scopus subject areas

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