Nonphotochemical Synthesis and Structure of the First Donor-Stabilized Bis(silylene)ruthenium Complex

Hiromi Tobita; Hiroaki Wada; Keiji Ueno; Hiroshi Ogino

doi:10.1021/om00019a003

Nonphotochemical Synthesis and Structure of the First Donor-Stabilized Bis(silylene)ruthenium Complex

Hiromi Tobita, Hiroaki Wada, Keiji Ueno, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph₃P)Ru(SiMe₂---O(Me)---SiMe₂), has been synthesized by the thermal reaction of CpRu-(PPh₃)₂Me with HMe₂SiSiMe₂OMe. The X-ray crystal structure analysis of this complex revealed its distortedpiano-stool structure, containing a RuSi₂O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.

Original language	English
Pages (from-to)	2545-2547
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	7
DOIs	https://doi.org/10.1021/om00019a003
Publication status	Published - 1994 Jul 1

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title = "Nonphotochemical Synthesis and Structure of the First Donor-Stabilized Bis(silylene)ruthenium Complex",

abstract = "The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru(SiMe2---O(Me)---SiMe2), has been synthesized by the thermal reaction of CpRu-(PPh3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure analysis of this complex revealed its distortedpiano-stool structure, containing a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.",

author = "Hiromi Tobita and Hiroaki Wada and Keiji Ueno and Hiroshi Ogino",

year = "1994",

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doi = "10.1021/om00019a003",

language = "English",

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T1 - Nonphotochemical Synthesis and Structure of the First Donor-Stabilized Bis(silylene)ruthenium Complex

AU - Tobita, Hiromi

AU - Wada, Hiroaki

AU - Ueno, Keiji

AU - Ogino, Hiroshi

PY - 1994/7/1

Y1 - 1994/7/1

N2 - The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru(SiMe2---O(Me)---SiMe2), has been synthesized by the thermal reaction of CpRu-(PPh3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure analysis of this complex revealed its distortedpiano-stool structure, containing a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.

AB - The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru(SiMe2---O(Me)---SiMe2), has been synthesized by the thermal reaction of CpRu-(PPh3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure analysis of this complex revealed its distortedpiano-stool structure, containing a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.

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DO - 10.1021/om00019a003

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EP - 2547

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Nonphotochemical Synthesis and Structure of the First Donor-Stabilized Bis(silylene)ruthenium Complex

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